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. 2022 Oct 10;27(19):6759. doi: 10.3390/molecules27196759

Scheme 3.

Scheme 3

Biosynthesis pathway of aspinonene (128) [100]. PKS: Polyketide synthase; MO: monooxygenase; Path A: 1,2-addition + allylic rearrangement; Path B: 1,4-addition.