) and 0.20 M HClO4 (
). The experimental data are divided into three regions: (A) 51 Gy min−1 at 36 °C (solid curve), (B) 150 Gy min−1 at 40 °C (dashed curve), and (C) 250 Gy min−1 at 42 °C (dash–dot curve). Lines are predicted values from multiscale modelling calculations using eqn (20) (
,
) and eqn (21) (
,
) for the reaction of AHA + H˙ in 0.20 M HClO4 and H2O respectively.