Measured second-order rate coefficients (k) for the reactions of the protonated (CH3CONHOH) and deprotonated (CH3CONHO−) forms of AHA (pKa = 8.7) and NH3OH+ (pKa = 6.17) with the eaq−, H˙ atom, and ˙OH radical at room temperature.
| Radical species | Second-order rate coefficient (k, M−1 s−1) | ||
|---|---|---|---|
| CH3CONHOH | CH3CONHO− | NH3OH+ | |
| eaq− | (6.02 ± 0.86) × 108 | — | (2.55 ± 0.10) × 109 |
| H˙ | (5.43 ± 0.56) × 106 | — | (4.01 ± 0.43) × 105 |
| ˙OH | (4.75 ± 0.76) × 108 | (3.86 ± 0.11) × 109 | (1.59 ± 0.06) × 109 |