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. 2022 Oct 18;12(46):29757–29766. doi: 10.1039/d2ra03392e

Measured second-order rate coefficients (k) for the reactions of the protonated (CH3CONHOH) and deprotonated (CH3CONHO) forms of AHA (pKa = 8.7) and NH3OH+ (pKa = 6.17) with the eaq, H˙ atom, and ˙OH radical at room temperature.

Radical species Second-order rate coefficient (k, M−1 s−1)
CH3CONHOH CH3CONHO NH3OH+
eaq (6.02 ± 0.86) × 108 (2.55 ± 0.10) × 109
(5.43 ± 0.56) × 106 (4.01 ± 0.43) × 105
˙OH (4.75 ± 0.76) × 108 (3.86 ± 0.11) × 109 (1.59 ± 0.06) × 109