REAGENT or RESOURCE	SOURCE	IDENTIFIER
Biological samples
Tococa quadrialata leaves	this paper	NCBI:txid427262
Chemicals, peptides, and recombinant proteins
n-bromodecane	Sigma-Aldrich	145785, CAS:112-29-8
Jasmonic acid (JA)	synthesized by Anja David, MPI-CE	adavid@ice.mpg.de, CAS: 77026-92-7
15N-Glycine	Eurisotope	NLM-202-1
D6-JA	HPC Standards GmbH	674797
D6-ABA	Toronto Research Chemicals	A110002
D4-SA	Santa Cruz Biotechnology	sc-212908
D6-JA-Ile	HPC Standards GmbH	674798
algal labelled amino acid mix	Isotec	T81-11001, Sigma-Aldrich:487910
13C6-glucose	Sigma-Aldrich	389374
13C6-fructose	Toronto Research Chemicals	F792546
DNaseI	ZymoResearch	E1010
vescalagin	Sigma-Aldrich	76418-5MG, CAS: 36001-47-5
α-pinene	Fluka	80604, CAS: 7785-70-8
(E)-β-ocimene	Firmenich	948840, CAS: 3779-61-6
(E)-DMNT	synthesized by Stefan Bartram, MPI-CE	bartram@ice.mpg.de, CAS: 19945-61-0
α-copaene	Fluka	27814, CAS: 3856-25-5
(E)-β-caryophyllene	Sigma-Aldrich	C9653, CAS: 87-44-5
α-humulene	Sigma-Aldrich	53675, CAS: 6753-98-6
germacrene D	Isolated by Stefan Bartram, MPI-CE	bartram@ice.mpg.de, CAS: 37839-63-7
α-farnesene	Sigma-Aldrich	W383902, CAS: 502-61-4
indole	Sigma-Aldrich	I3408, CAS: 120-72-9
methyl anthranilate	Sigma-Aldrich	M29703, CAS: 134-20-3
2-heptanone	Sigma-Aldrich	537683, CAS: 110-43-0
2-heptanol	Fluka	51800, CAS: 543-49-7
oct-1-en-3-ol	Fluka	74950, CAS: 3391-86-4
3-octanone	Merck	821860, CAS: 106-68-3
octan-3-ol	Sigma-Aldrich	218405, CAS: 589-98-0
benzyl cyanide	Merck	8.01811, CAS: 140-29-4
Critical commercial assays
Spectrum Plant Total RNA Kit	Sigma-Aldrich	STRN50
One-Step PCR Inhibitor Removal Kit	ZymoResearch	D6030
Deposited data
Raw reads (transcriptome sequencing)	this paper	PRJNA865704
Experimental models: Organisms/strains
Tococa quadrialata	this paper	NCBI:txid427262
Azteca spp.	this paper	NCBI:txid121511
Spodoptera spp.	this paper	NCBI:txid7106
Software and algorithms
ImageJ	Schneider et al. (2012)	https://imagej.nih.gov/ij/
NIST/EPA/NIH EI Mass Spectral Library	National Institute of Standards and Technology	https://chemdata.nist.gov/dokuwiki/doku.php?id=chemdata%3Adownloads%3Astart#nist_epa_nih_mass_spectral_database
Analyst 1.6.3	Applied Biosystems	https://sciex.com/products/software/analyst-software
Metaboscape software	Bruker Daltonics	https://www.bruker.com/en/products-and-solutions/mass-spectrometry/ms-software/metaboscape.html
CLC Genomics Workbench	Qiagen Bioinformatics	https://www.qiagen.com/us/products/discovery-and-translational-research/next-generation-sequencing/informatics-and-data/analysis-and-visualization/clc-genomics-workbench/
OmicsBox software	biobam	https://www.biobam.com/omicsbox/
R	RStudio_Team (2021)	http://www.rstudio.com/
OriginPro	OriginLab Corporation	https://www.originlab.com/
SciFinder	CAS	https://scifinder.cas.org
Other
PoraPak filter	Material: Alltech, packed filters bought from http://www.volatilecollectiontrap.com/main.sc	VCT-1/4-3-POR-Q-25MG
GC-MS	Agilent Technologies	Agilent 6890 GC & 5973 MS
Optima-5 column	Macherey-Nagel	726056.30
PET bags	Toppits®	Bratschlauch
HPLC	Agilent Technologies	Agilent 1260 & Agilent 1100
Zorbax Eclipse XDB-C18 column (API6500)	Agilent Technologies	927975-902
Zorbax Eclipse XDB-C18 column (timsToF)	Agilent Technologies	981758-902
QTRAP 6500 tandem mass spectrometer	AB Sciex	https://sciex.com/products/mass-spectrometers
HILIC column	Supelco	56401AST
ESI iontrap mass spectrometer	Bruker Daltonics	Esquire 6000 https://www.bruker.com/en/products-and-solutions/mass-spectrometry/esi-ion-trap.html
Phenyl-Hexyl column	Phenomenex	00F-4257-E0
Dionex Ultimate 3000 series UHPLC	Thermo Scientific	https://www.thermofisher.com/de/en/home.html
Bruker timsToF mass spectrometer	Bruker Daltonics	timsTOF https://www.bruker.com/en/products-and-solutions/mass-spectrometry/timstof/timstof.html
isotope ratio mass spectrometer	Thermo Finnigan	Delta + XL
elemental analyzer	CE Instruments	NA1110 (now EA1110, part N° 112 110 52)