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. 2022 Oct 3;13(40):11863–11868. doi: 10.1039/d2sc04271a

Association constants (M−1) for formation of 1 : 1 complexes with tri-n-butyl phosphine oxide in n-octane at 298 Ka.

X K(Y = OH) K′(Y = H) K/K
H 940 ± 140 202 ± 17 4.7
Me 650 ± 140 120 ± 20 5.4
OMe 1800 ± 300 220 ± 140 8.2
CF3 8790 ± 60 1030 ± 50 8.5
NO2 46 000 ± 8000 3840 ± 90 12.0
a

Average values from at least 3 experiments with errors at the 95% confidence limit.