Association constants (M−1) for formation of 1 : 1 complexes with tri-n-butyl phosphine oxide in n-octane at 298 Ka.
X | K(Y = OH) | K′(Y = H) | K/K′ |
---|---|---|---|
H | 940 ± 140 | 202 ± 17 | 4.7 |
Me | 650 ± 140 | 120 ± 20 | 5.4 |
OMe | 1800 ± 300 | 220 ± 140 | 8.2 |
CF3 | 8790 ± 60 | 1030 ± 50 | 8.5 |
NO2 | 46 000 ± 8000 | 3840 ± 90 | 12.0 |
Average values from at least 3 experiments with errors at the 95% confidence limit.