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. 2022 Oct 7;13:973255. doi: 10.3389/fphar.2022.973255

TABLE 2.

Phytochemical profile by LC-ESI-QTOF-MS of Brazilian Organic Propolis mix.

Peak number Compound name Molecular formula Exact Mass (g/mol) [M-H]- Fragments MS (m/z)
1 Gallic acid C7H6O5 170.0216 169.0143 125.0239
2 Caffeic acid C7H6O4 180.0424 179.0351 135.0452
3 Coumaric acid C9H8O3 164.0474 163.0402 147.0443
4 Caffeoyltartaric acid C13H11O9 312.0482 311.0417 135.0300; 149.0288; 179.0133
5 3,4-Dicaffeoylquinic acid C25H24O12 516.1270 515.1159 135.0305; 161.0066; 179.0145
6 Quercetin C15H10O7 302.0430 301.0367 124.0018; 151.9938; 227.0444
7 Gibberellin A7 C19H22O5 330.1467 329.1379 255.1454
8 Gibberellin A20 C19H24O5 332.1624 331.1524 257.1618; 301.1453; 331.1512
9 Gibberellin A9 C19H24O4 316.16746 315.1588 315.1582
10 Artepillin C C19H24O3 300.1725 299.1641 255.1760; 200.1198; 145.0683

Bold values are the main fragments.