Table 5.

Results of cyclic voltammetry of bis-μ-oxo bridged Mn(III,IV) dimers.

Complex	MnIII,IV/MnIV,IV [V] vs. NHE	MnIII,IV/MnIII,III [V] vs. NHE	Solvent and Electrolyte	Ref.
1 b	1.50	0.54	CH3CN, 0.3 M Et4NCIO4	[15d]
2a	1.28	0.34	CH3CN, 0.1 M Et4NCIO4	[16]
2b	1.51	0.59	CH3CN, 0.3 M Et4NCIO4	[15d]
3a	0.99	0.38	H2O (pH 7.0), 0.1 M NaCIO4	[15e]
	1.06	0.35	CH3CN, 0.1 M NaCIO4
3b	1.00	0.39	H2O (pH 7), 0.1 M NaClO4	[18]
4a	1.14[a]	0.44[b]	H2O (pH 6.9)	[4]
4b	1.29	0.49	CH3CN, 0.1 M Bu4NPO4	[15h]
5a	1.40	0.66	[c]	[15g]
6 a	1.25	0.13	CH3CN, 0.1 M Bu4NPF6	[1b,15f]
	1.22	0.22	CH3CN, 0.1 M Bu4NPF6
7a	1.14	0.39	CH3CN, 0.1 M Bu4NPF6	[15f,22]
	1.04	0.27	CH3CN, 0.1 M Bu4NPO4
10	0.99	0.24	H2O (pH 7.0), 0.1 M KCl	[26]

^[a]Quasi-reversible oxidation wave.

^[b]Irreversible reduction event.

^[c]Details not available.