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. Author manuscript; available in PMC: 2023 Jul 8.
Published in final edited form as: Eur J Inorg Chem. 2022 Apr 7;2022(19):e202200039. doi: 10.1002/ejic.202200039

Table 7.

Tmpa derived Mn(III,IV) dimer complexes.

Complex Coordinating Ligand Metal Complex Ref.
4a tris(2-methylpyridyl)amine (tmpa) [(tmpa)2Mn2O2][S2O6]3/2·7H2O [4]
4b tris(2-methylpyridyl)amine (tmpa) [(tmpa)2Mn2O2][CIO4]3·3 H2O [15h]
4.1a (2-(2-pyridyl)ethyl)bis(2-pyridylmethyl)amine (pmea) [(pmea)2Mn2O2][CIO4]3
4.2 a (1-(2-pyridyl)ethyl)(2-(2-pyridyl)ethyl)(2-pyridylmethyl)amine (Mepmeal) [(Mepmea1)2Mn2O2][CIO4]3 [38]
4.3 a ((6-methyl-2-pyridyl)methyl))(2-(2-pyridyl)ethyl)(2-pyridylmethyl)amine (Mepmea2) [(Mepmea2)Mn2O2][CIO4]3
4.4 a ((6-methyl-2-pyridyl)methyl)bis(2-pyridylmethyl)amine (Mepmea3) [(Mepmea3)Mn2O2][CIO4]3
4.5 a (bis[2-(2-pyridyl)ethyl]-2-pyridylmethylamine (pmap) [(pmap)2Mn2O2][ClO4]3·CH3CN [37]