Table 8.
Mn(III) monomeric complexes with various tetraaza macrocyclic ligands.
| Coordinating Ligand | Metal Complex | Ref. | |
|---|---|---|---|
|
| |||
| 11a | meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (tet a) | [MnIII(tet a)CI2][PF6] | |
| ]11b | meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (tet a) | [MnIII(tet a)CI2][BF4] | |
| 11c | meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (tet a) | [MnIII(tet a)Br2][PF6] | [48] |
| 11 d | meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (tet a) | [MnIII(tet a)(NCS)2][NCS] | |
| 11 e | meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (tet a) | [MnIII(tet a)CI2][Cl]·3H2O | |
| 11f | meso-5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (tet a) | [MnIII(tet a)Cl2][Cl]·1.5H2O | [47b] |
| 12a | rac-5,7,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (tet b) | [MnIII(tet b)Cl2][PF6] | [49] |
| 12b | rac-5,7,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (tet b) | [MnIII(tet b)Br2][PF6] | |
| 12c | rac-5,7,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (tet b) | [MnIII(cyclam)Cl2[Cl]·4H2O | [47b] |
| 13a | 1,4,8,11-tetraazacyclotetradecane (cyclam) | [MnIII(cyclam)Cl2][Cl] | [50] |
| 13b | 1,4,8,11-tetraazacyclotetradecane (cyclam) | [MnIII(cyclam)Br2][Br] | [50,51] |
| 13c | 1,4,8,11-tetraazacyclotetradecane (cyclam) | [MnIII(cyclam)(NCS)2][NCS] | |
| 13d | 1,4,8,11-tetraazacyclotetradecane (cyclam) | [MnIII(cyclam)(N3)2][ClO4] | [50] |
| 13e | 1,4,8,11-tetraazacyclotetradecane (cyclam) | [MnIII(cyclam)Br2][PF6] | [52] |
| 13f | 1,4,8,11-tetraazacyclotetradecane (cyclam) | [MnIII(cyclam)CI2][BF4] | |
| 13g | 1,4,8,11-tetraazacyclotetradecane (cyclam) | [MnIII(cyclam)Cl2][CF3SO3] | [47b] |
| 13h | 1,4,8,11-tetraazacyclotetradecane (cyclam) | [MnIII(cyclam)(NO3)2][NO3] | [51] |
| 13 i | 1,4,8,11-tetraazacyclotetradecane (cyclam) | [MnIII(cyclam)Cl2][NO3] | |
| 13j | 1,4,8,11-tetraazacyclotetradecane (cyclam) | [MnIII(cyclam)CI2][Cl]·5H2O | [8,51] |
| 13k | 1,4,8,11-tetraazacyclotetradecane (cyclam) | [MnIII(cyclam)(CN)2][CIO4] | [51] |
| 13 l [a] | 1,4,8,11-tetraazacyclotetradecane (cyclam) | [MnIII(cyclam)Br2][Br]·H2O | |
| 13m [a] | 1,4,8,11-tetraazacyclotetradecane (cyclam) | [MnIII(cyclam)Cl2][Cl]·0.33CH3OH | [8] |
| 13n | 1,4,8,11-tetraazacyclotetradecane (cyclam) | [MnIII(cyclam)(OH2)2][CF3SO3)3·H2O | |
| 13o | 1,4,8,11-tetraazacyclotetradecane (cyclam) | [MnIII(cyclam)I2][I] | |
| 13p | 1,4,8,11-tetraazacyclotetradecane (cyclam) | [MnIII(cyclam)(ONO)2][ClO4] | [53] |
| 13q | 1,4,8,11-tetraazacyclotetradecane (cyclam) | [MnIII(cyclam)(OClO3)2][ClO4] | |
| 13 r | 1,4,8,11-tetraazacyclotetradecane (cyclam) | [MnIII(cyclam)(CH3COO)(CH3COOH)][ClO4]2 | |
| 13s | 1,4,8,11-tetraazacyclotetradecane (cyclam) | [MnIII(cyclam)(N3)2[CF3SO3] | |
| 14a | 1,4,8,12-tetraazacylcotetradecane (cyclal) | [MnIII(cyclal)Br2][PF6] | [52] |
| 14b | 1,4,8,12-tetraazacylcotetradecane (cyclal) | [MnIII(cyclal)Cl2][Cl]·H2O | [54] |
| 15a | 5-imidazole-1,4,8,11-tetraazacyclotetradecane (imcyclam) | [MnIII(imcyclam)(ClO4)][ClO4]2 | [55] |
| 15b | 5-imidazole-1,4,8,11-tetraazacyclotetradecane (imcyclam) | [MnIII(imcyclam)Cl][ClO4]2 | |
| 16 | 1,4,7,11-tetrazacyclotetradecane (isocyclam) | [MnIII(isocyclam)Cl2][Cl]·2H2O | [26] |
| 19 [a] | 1,4,7,10-tetraaza-2,6-pyridinophane (pyclen) | [MnIII(pyclen)Cl2][ClO4] | [25] |
| 20a [a] | 4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane (etcyclam) | [MnIII(etcyclam)Cl2][PF6] | |
| 20b [a] | 4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane (etcyclam) | [MnIII(etcyclam)(N3)2][PF6] | |
| 20c [a] | 4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane (etcyclam) | [MnIII(etcyclam)(OH)(OAc)][PF6] | [47a] |
| 20d [a] | 4,11-dimethyl-1,4,8,11-tetraazabicyclo[6.6.2]hexadecane (etcyclam) | [MnIII(etcyclam)(OMe)2][PF6] | |
| 21 [a] | 4,10-dimethyl-1,4,7,10-tetraazabicyclo[5.5.2]tetradecane (etcyclen) | [MnIII(etcyclen)Cl2][PF6] | |
[a]
Indicates complex is in the cis-geometry, all others are in the trans-geometry.