Table 3.
Monomer coupling, and cross-coupling patterns extracted from literature. M1, M2 represent the individual monomer unit and O1 and O2 represent two or more units connected forming a lignin chain (L).
| Linear | Branched | |||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Dimer structures | Oligomer and monomer | Oligomer cross-coupling | ||||||||||
| M1 | M2 | β-O-4 | β-β | β-5 | O1 | M1 | β-O-4 | β-5 | O1 | O2 | 4-O-5 | 5-5 |
| G | G | ✓ | ✓ | ✓ | L-G | G | ✓ | ✓ | L-G | L-G | ✓ | ✓ |
| S | S | ✓ | ✓ | ✗ | L-S | S | ✓ | ✗ | L-S | L-S | ✗ | ✗ |
| S | G | ✓ | ✓ | ✓ | L-S | G | ✓ | ✓ | L-G | L-S | ✗ | ✗ |
| G | S | ✓ | ✓ | ✗ | L-G | S | ✓ | ✗ | L-S | L-G | ✓ | ✗ |