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. 2022 Oct 25;12(47):30386–30403. doi: 10.1039/d2ra04667a

Reports that studied long-term stability of AgNPs.

Source of AgNPs synthesis Size range (nm) Storage conditions Stability Periodic evaluation Main physicochemical method used Application Periodic application evaluation Ref.
Cassia roxburghii DC (leaf aqueous extract) 10–30 Dark, room temperature 12 months Yes UV-vis Antifungal No 1
LASER ablation 10–70 Both light and dark, room temperature and 4 °C (only dark) 13.5 months No (only initial and final measurements) STEM coupled with EDX spectroscopy and mapping Antibacterial Yes (every 14 and 45 days) 18
Parachlorella kessleri (whole aqueous extract) 5–30 Both light and dark, room temperature and 5 °C (only dark) 6.6 months Yes UV-vis and TEM (size analysis) No No 27
Chemical reduction of AgNO3 with NaBH4 in the presence of Na3C6H5O7 2–10 Dark, room temperature and 4 °C 12 months No (only initial and final measurements) UV-vis and TEM (size analysis) No No 21
Chemical reduction of AgNO3 with NaBH4 in the presence of different stabilizing agents Not disclosed Both light and dark, room temperature and 4 °C (only dark) 6 months No (only initial and final measurements) UV-vis, zeta potential, ICP-MS, DLS, XRD and TEM (size analysis) Cytotoxic studies No (only initial and final measurements) 19
Chemical reduction of AgNO3 with NaBH4 in the presence of different stabilizing agents Not disclosed Dark, room temperature 6 months No (only initial and final measurements) UV-vis, zeta potential and DLS Detection of Mn2+ ions No 28
Annona muricata (ethanoic extract) 2–500 Dark, room temperature and cold storage (4, −20 and −80 °C) 3 months No (only final) UV-vis No No 29
Derris trifoliata seeds (aqueous extract) Not disclosed Dark, room temperature >3 months No Not disclosed Antioxidant, antibacterial and antiproliferative No 30
Juglans regia (aqueous extract) Not disclosed Dark, room temperature and 4 °C 6 months No Not disclosed Antioxidant, antimicrobial, cytotoxicity No 31
Chemical reduction using pectin 8–28 Dark, 4 °C 5 months Yes UV-vis Antibacterial No 32
Sargassum angustifolium aqueous extract along with chitosan 5–20 Dark room temperature 6 months No (only initial and final measurements) UV-vis Antibacterial No 33