Table 2. Selected Geometric Parameters for Silicon Halide PMe3 Complexes.
| [SiCl4(PMe3)2]14 | [SiCl3(PMe3)2][BArF] | [SiI3(PMe3)2][I] | |
|---|---|---|---|
| d(Si–X), Å | 2.2069(3) | 2.0828(15) | 2.503(4) |
| 2.2296(3) | 2.0811(15) | 2.471(7) | |
| 2.0866(14) | |||
| d(Si–P), Å | 2.3484(3) | 2.3276(14) | 2.380(5) |
| 2.3230(13) | |||
| C–P–C angles, ° | 104.76(5)–105.94(5) | 106.4(3)–108.2(3) | 104.2(7)–109.1(9) |