Table 1.
1H NMR and 13C NMR Spectroscopic Data for Compounds 1.
| Peripolin (1) | ||
|---|---|---|
| Position | δH (J in Hz) | δC Mult |
| 2 | 5.34 dd (2.90, 12.7) | 80.6, CH |
| 3a | 3.12 dd (12.7, 17.2) | 44.0, CH2 |
| 3b | 2.74 dd (2.9, 17.2) | 44.3, CH2 |
| 4 | 198.4, qC | |
| 5 | 164.9, qC | |
| 6 | 6.16 m, ar | 97.0, CH |
| 7 | 166.5, qC | |
| 8 | 6.14 m, ar | 98.1, CH |
| 9 | 164.6, qC | |
| 10 | 105.1. qC | |
| 1′ | 131.7, qC | |
| 2′ | 6.79 m, ar | 116.5, CH |
| 3′ | 147.0, qC | |
| 4′ | 146.6, qC | |
| 5′ | 6.80 m, ar | 119.4, CH |
| 6′ | 6.93 m, ar | 114.9, CH |
| 1″ | 5.08 d (7.6) | 99.5, CH |
| 2″ | 3.66 dd (7.7, 9.0) | 78.9, CH |
| 3″ | 3.60 dd (8.3, 9.0) | 79.1, CH |
| 4″ | 3.36 dd (8.3, 10.4) | 71.8, CH |
| 5″ | 3.69 ddd (2.0, 7.5, 11.9) | 75.5, CH |
| 6″a | 4.40 dd (2.0, 11.9) | 64.6, CH2 |
| 6″b | 4.19 dd (7.5, 11.9) | |
| 1‴ | 5.25 d (1.4) | 102.5, CH |
| 2‴ | 3.93 dd (1.4, 3.2) | 72.2, CH |
| 3‴ | 3.0 m | 72.3, CH |
| 4‴ | 3.40 dd (1.6, 9.5) | 74.1, CH |
| 5‴ | 3.90 ddd (3.9, 6.2, 9.5) | 70.0, CH |
| 6‴ | 1.30 d (6.2) | 18.2, CH3 |
| 1⁗ | 172.5, qC | |
| 2⁗ | 2.72–2.52 m | 45.0, CH2 |
| 3⁗ | 70.7, qC | |
| 4⁗ | 2.72–2.52 m | 46.5, CH2 |
| 5⁗ | 174.9, qC | |
| 6⁗ | 1.27 s | 27.7, CH3 |