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. 2022 Sep 6;13(41):11981–12015. doi: 10.1039/d2sc04012c

MOF derivatives as electrode materials for MIHCs.

MOF precursors MOF derivatives Applications Configurations Energy density (W h kg−1) Power density (W kg−1) Cycling stability Ref
MOF-derived metal compounds
Fe-MOF α-Fe2O3 HPNP LIHC α-Fe2O3 HPNP//carbon spheres 107 9680 2500 cycles (1 A g−1) 149
CoZn-ZIF Ti3C2@Co3O4/ZnO LIHC Ti3C2@Co3O4/ZnO//AC 196.8 3500 6000 cycles (2 A g−1) 86
MOF-derived carbons
Fe-BTC Onion-like carbons LIHC Onion-like carbon//AC 224 14 436 4000 cycles (1 A g−1) 87
ZIF-8 N-doped microporous carbon@rGO PIHC N-doped microporous carbon@rGO//AC 158.1 19 091 12 000 cycles (2 A g−1) 170
ZIF-8 Necklace-like N-doped carbon ZIHC Zn//necklace-like N-doped carbon 189.6 11 261.3 50 000 cycles (5 A g−1) 171
ZIF-8 N, P-doped open carbon cage ZIHC Zn//N, P-doped open carbon cage 97 6500 300 000 cycles (50 A g−1) 83
ZnCo-MOF N-doped porous carbon ZIHC Zn//N-doped porous carbon 157.6 10 000 cycles (5 A g−1) 79
ZIF-8 N, O-doped carbon ZIHC Zn//N, O-doped carbon 110 20 000 10 000 cycles (5 A g−1) 174
ZIF-8 N, P, O tri-doped carbon ZIHC Zn/carbon cloth@ZIF-8//N, P, O tri-doped carbon 43 137 900 10 000 cycles (10 A g−1) 89
Mn-MOF Porous carbon PIHC Porous carbon//AC 120 26 000 120 000 cycles (2 A g−1) 185
MOF-derived metal/carbons
ZIF-67 CoSnx/carbon nanofibers LIHC CoSnx/carbon nanofiber//porous carbon 143 22 800 5000 cycles (2 A g−1) 189
NENU-5 MoO2@rGO LIHC MoO2@rGO//PANI@rGO 242 28 750 10 000 cycles (5 A g−1) 78
Mn-MOF MnO2@C LIHC MnO2@C//nanoporous carbon 166 3500 5000 cycles (1 A g−1) 74
Nb-MOF Nb2O5@C/rGO LIHC Nb2O5@C/rGO//AC 71.5 3900 2500 cycles (0.2 A g−1) 191
NH2-MIL-125 (Ti) TiOxNy/C SIHC TiOxNy/C/N-doped carbon 80 4000 1200 cycles (0.8 A g−1) 72
MIL-125 (Ti) TiO2/C@NPSC PIHC TiO2/C@NPSC//AC 114 21 000 10 000 cycles (1 A g−1) 80
V-MOF V2O3/N-doped carbon SIHC V2O3/N-doped carbon//AC 63 5805 5000 cycles (1 A g−1) 73
ZIF-8 ZnS@C SIHC Nanoporous carbon//ZnS@C 38.3 4000 cycles (20 A g−1) 194
Sn-MOF NG@SnSe/C SIHC NG@SnSe/C//AC 115.5 5742 1100 cycles (0.5 A g−1) 77
ZIF-67 CoTe2@N–C LIHC CoTe2@N–C//porous carbon 144.5 10 000 1000 cycles (1 A g−1) 197
ZnCo-ZIF Co3ZnC@NC LIHC Co3ZnC@NC//microporous carbon 141.4 10 300 1000 cycles (1 A g−1) 71