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fugacity (Pa) |
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residual Gibbs energy (J) |
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residual Gibbs energy of the adsorbed phase (J) |
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dimensionless Henry law constant (–) |
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Henry law constant (mol kg–1 Pa–1) |
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adsorbed amount of component i (mol kg–1) |
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saturation capacity of component i (mol kg–1) |
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number of moles (mol) |
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number of moles of species (mol) |
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size of lattice in mole equivalents (mol) |
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mass of species (kg) |
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mass of solid (kg) |
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molecular mass of species (kg mol–1) |
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pressure (Pa) |
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reference pressure (Pa) |
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reduced pressure (–) |
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characteristic pressure of the mixture (Pa) |
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characteristic pressure of component pure (Pa) |
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characteristic pressure of component in the adsorbed phase (Pa) |
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characteristic pressure of the solid (Pa) |
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pair characteristic pressure (Pa) |
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average number of mers in a molecule (–) |
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number of mers in molecule in the mixture (–) |
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number of mers in molecule pure (–) |
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ideal gas constant (J mol–1 K–1) |
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temperature (K) |
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reduced temperature (–) |
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characteristic temperature of the mixture (K) |
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characteristic temperature of component pure (K) |
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characteristic temperature of the solid (K) |
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reduced molar volume (–) |
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average close-packed volume of mers in a mixture (m3 mer-mol–1) |
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close-packed volume of mers molecule pure (m3 mer-mol–1) |
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close-packed volume of mers molecule in the adsorbed phase (m3 mer-mol–1) |
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volume of the lattice (m3) |
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close-packed volume for the mixture (m3) |
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volume of the solid (m3) |
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mass fraction of species (–) |
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mole fraction of species in the adsorbed phase (–) |
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mole fraction of species in the fluid phase (–) |
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compressibility factor (–) |
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compressibility factor derived from the Helmholtz energy (–) |