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. 2022 Oct 18;12(10):1009. doi: 10.3390/membranes12101009
βT isothermal solid compressibility (Pa–1)
ΔH0 adsorption enthalpy at zero loading (J mol–1)
ΔU0 adsorption energy at zero loading (J mol–1)
φi fugacity coefficient of species i (–)
ϕj volume fraction in the lattice occupied by species j at close-packing (–)
ϕS volume fraction in the lattice occupied by the solid at close-packing (–)
ϕjL volume fraction in the lattice occupied by species j (–)
κij pair interaction coefficient (–)
μiR residual chemical potential of species i in the adsorbed phase (J mol–1)
μiFR residual chemical potential of species i in the fluid phase (J mol–1)
μiR residual chemical potential of species i at infinite dilution in the adsorbed phase (J mol–1)
μSRm residual chemical potential of the solid on a mass basis (J kg–1)
μS0Rm residual chemical potential of the solid without adsorbates (J kg–1)
ρ˜ reduced mass density (–)
ρ* average close-packed mass density in a mixture (kg m–3)
ρj* close-packed mass density of molecule j (kg m–3)
ρjA* close-packed mass density of molecule j in the adsorbed phase (kg m–3)
ρS mass density of the solid (kg m–3)
ξjA volume correction due to confinement constraints (–)
Ψ reduced grand potential (mol kg–1)