Skip to main content
. 2022 Oct 17;27(20):6967. doi: 10.3390/molecules27206967

Table A6.

Photophysical properties of p-block mono(dipyrrinato) (DIPY) complexes.

DIPY Solvent λa (nm) ɛ a λf (nm) ∆ṽ0 b [∆ṽref] c
(cm−1)
φf Ref.
B-2 MeOH 502 12 508 235 0.70 [55]
B-3 MeOH 534 11 548 478 0.02 [55]
B-5 Tol:MeOH (99:1) 626 645 471 0.72 [119]
Ga-8 DCM 494 501 283 0.82 [113]
Tol 497 505 319 0.91 [113]
Al-12 Tol:MeOH (99:1) 624 650 641 [560] 0.23 [119]
Al-13 Tol:MeOH (99:1) 625 647 544 0.72 [119]
Al-14 d Tol:MeOH (99:1) 607 620 345 [360] 0.55 [119]
Al-15 d Tol:MeOH (99:1) 607 620 345 0.56 [119]
Al-16 d Tol:MeOH (99:1) 608 619 292 0.83 [119]

a ɛ (104 M−1 cm−1), b Calculated with Equation (7), c literature value, d with excess amount of Zn(II) salt to prevent dissociation.