Table 1. Thermal Properties of Compounds 1–4 in Their E Isomeric Forms and Their Z-to-E Isomerization Process.
E |
Z → E |
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---|---|---|---|---|---|---|---|---|
Tm (°C) | ΔHm (kJ/mol) | ΔHm (J/g) | Tiso (°C) | ΔHiso (kJ/mol) | ΔHiso (J/g) | ΔHtotal (kJ/mol) | ΔHtotal (J/g) | |
1 | 83 | 21 | 97 | 109 | 51 | 234 | 72 | 331 |
2 | 76 | 19 | 81 | 110 | 50 | 216 | 69 | 297 |
3 | 113 | 28 | 114 | 112 | 49 | 200 | 77 | 314 |
4 | liq. | liq. | liq. | 111 | 50 | 203 | 50 | 203 |