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. 2022 Oct 12;144(42):19430–19436. doi: 10.1021/jacs.2c07537

Table 1. Thermal Properties of Compounds 1–4 in Their E Isomeric Forms and Their Z-to-E Isomerization Process.

  E
Z → E
   
  Tm (°C) ΔHm (kJ/mol) ΔHm (J/g) Tiso (°C) ΔHiso (kJ/mol) ΔHiso (J/g) ΔHtotal (kJ/mol) ΔHtotal (J/g)
1 83 21 97 109 51 234 72 331
2 76 19 81 110 50 216 69 297
3 113 28 114 112 49 200 77 314
4 liq. liq. liq. 111 50 203 50 203