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Total biosynthesis of ilicicolin H (60). (A) Organization and predicted gene functions of the ncc and icc BGCs. Black ORFs encode for enzymes involved in the biosynthesis of 60. (B) Proposed biosynthesis of 60. (D) Inverse-electron-demand Diels–Alder (IEDDA) and normal-electron-demand Diels–Alder (NEDDA) reactions. EWG: electron-withdrawing group. EDG: electron-donating group.
