Data for FRP (co-)polymerisations using HEAA-PCL macromonomers.
| Polymer | Ratio (HEAA-PCL) : comonomer | Conversiona (%) | M n GPCb (kDa) | M w GPCb (kDa) | Đ b |
|---|---|---|---|---|---|
| Poly-(HEAA-PCL)44 | 1 : 0 | Quant. | 14.1 | 21.9 | 1.6 |
| (HEAA-PCL)44-co-PEGMA | 4 : 6 | 99 | 5.39 | 9.66 | 1.8 |
| (HEAA-PCL)44-co-PEGMA | 7 : 3 | 94 | 11.2 | 15.8 | 1.4 |
| Poly-(HEAA-PCL)15 | 1 : 0 | Quant. | 9.18 | 13.2 | 1.4 |
| (HEAA-PCL)15-co-PEGMA | 4 : 6 | 98 | 4.00 | 5.36 | 1.3 |
| (HEAA-PCL)15-co-PEGMA | 7 : 3 | 99 | 5.71 | 8.87 | 1.6 |
| (HEAA-PCL)10-co-HEAA | Approx. 1.80 : 0.17 | Quant. | 8.90 | 15.4 | 1.7 |
a
Determined by 1H-NMR spectroscopy deemed quantitative when no olefinic protons visible in the spectrum.
b
Determined by GPC in THF.