Table 4. Theoretical and Experimental (Solid-State) Thermodynamic Parameters for Complexes 1–3.

complexes	ΔH (kJ mol–1) (exp.)	ΔH (kJ mol–1) (calc.)	ΔS (J mol–1 K–1) (exp.)	ΔS (J mol–1 K–1) (calc.)	T1/2 (K) (exp.)	T1/2 (K) (calc.)
1	20.06	12.744	91.66	60.183	219	211
2	8.82	19.707	35.16	61.367	251	321
3	20.07	19.949	54.85	60.467	366	329