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. 2022 Oct 19;7(43):38856–38868. doi: 10.1021/acsomega.2c04587

Table 3. CO2 Capture Capacity at 5 and 30 °C, Calculated Based on TG-TPD Curves, of Mg(OH) + x % F Adsorbents Calcined, for 3 h in Air, at 400 and 500 °Ca.

  calcined at 400 °C
calcined at 500 °C
adsorbent total % mass loss (RT–420 °C) *total mgCO2·g–1(RT–420 °C) **total (mmolCO2·g–1)(RT–420 °C) total % mass loss (RT–420 °C) *total mgCO2·g–1(RT–420 °C) **total (mmolCO2·g–1)(RT–420 °C) total % mass loss (RT–520 °C) total mgCO2·g–1(RT–520 °C) total (mmolCO2·g–1)(RT–520 °C)
CO2 Capture at 5 °C
Mg(OH)2 + 20% F 10.39 103.9 2.36 7.73 77.3 1.76 8.21 82.1 1.86
Mg(OH)2 + 30% F 7.76 77.6 1.76 7.28 72.8 1.65 7.78 77.8 1.77
Mg(OH)2 + 40% F 4.77 49.5 1.13 4.47 44.7 1.02 4.73 47.3 1.07
Mg(OH)2 + 50% F 3.94 39.6 0.90 2.78 27.8 0.63 2.89 28.9 0.66
CO2 Capture at 30 °C
Mg(OH)2 + 20% F 8.94 89.4 2.03 5.24 52.4 1.19 5.56 55.5 1.26
Mg(OH)2 + 30% F 6.20 61.9 1.41 4.64 46.4 1.05 4.99 49.9 1.13
Mg(OH)2 + 40% F 4.00 39.9 0.91 2.97 29.7 0.68 3.14 31.4 0.71
Mg(OH)2 + 50% F 3.22 32.2 0.73 1.99 19.9 0.45 2.09 20.9 0.47
a

*,** for comparison at the same temperature range (RT–420 °C).