Table 3. CO2 Capture Capacity at 5 and 30 °C, Calculated Based on TG-TPD Curves, of Mg(OH) + x % F Adsorbents Calcined, for 3 h in Air, at 400 and 500 °Ca.
calcined
at 400 °C |
calcined
at 500 °C |
||||||||
---|---|---|---|---|---|---|---|---|---|
adsorbent | total % mass loss (RT–420 °C) | *total mgCO2·g–1(RT–420 °C) | **total (mmolCO2·g–1)(RT–420 °C) | total % mass loss (RT–420 °C) | *total mgCO2·g–1(RT–420 °C) | **total (mmolCO2·g–1)(RT–420 °C) | total % mass loss (RT–520 °C) | total mgCO2·g–1(RT–520 °C) | total (mmolCO2·g–1)(RT–520 °C) |
CO2 Capture at 5 °C | |||||||||
Mg(OH)2 + 20% F | 10.39 | 103.9 | 2.36 | 7.73 | 77.3 | 1.76 | 8.21 | 82.1 | 1.86 |
Mg(OH)2 + 30% F | 7.76 | 77.6 | 1.76 | 7.28 | 72.8 | 1.65 | 7.78 | 77.8 | 1.77 |
Mg(OH)2 + 40% F | 4.77 | 49.5 | 1.13 | 4.47 | 44.7 | 1.02 | 4.73 | 47.3 | 1.07 |
Mg(OH)2 + 50% F | 3.94 | 39.6 | 0.90 | 2.78 | 27.8 | 0.63 | 2.89 | 28.9 | 0.66 |
CO2 Capture at 30 °C | |||||||||
Mg(OH)2 + 20% F | 8.94 | 89.4 | 2.03 | 5.24 | 52.4 | 1.19 | 5.56 | 55.5 | 1.26 |
Mg(OH)2 + 30% F | 6.20 | 61.9 | 1.41 | 4.64 | 46.4 | 1.05 | 4.99 | 49.9 | 1.13 |
Mg(OH)2 + 40% F | 4.00 | 39.9 | 0.91 | 2.97 | 29.7 | 0.68 | 3.14 | 31.4 | 0.71 |
Mg(OH)2 + 50% F | 3.22 | 32.2 | 0.73 | 1.99 | 19.9 | 0.45 | 2.09 | 20.9 | 0.47 |
*,** for comparison at the same temperature range (RT–420 °C).