Table 1. Parameters Determined from Ellipsometry and Raman Spectra for Selected Samples Studied in This Worka.
deposition | Δn(2.5 eV) | ε∞ | Ep(eV) | Γp(eV) | ω (cm–1) | Δω (cm–1) |
---|---|---|---|---|---|---|
PEDOT:PSS Sigma-Aldrich 483095 (1:1.6 ratio by weight) | ||||||
BC | 0.20 | 2.68 | 1.28 | 0.51 | 1422 | 41 |
DC | 0.36 | 2.78 | 1.48 | 0.70 | 1422 | 41 |
DC & DMSO | 0.15 | 2.59 | 1.67 | 0.82 | 1427 | 41 |
PEDOT:PSS Heraeus Clevios AI4083 (1:6 ratio by weight) | ||||||
BC | 0.01 | 2.52 | 1.27 | 0.67 | 1437 | 44 |
BC | 0.12 | 2.58 | 1.03 | 0.72 | 1432 | 42 |
DC | 0.12 | 2.56 | 1.01 | 0.74 | 1431 | 43 |
DC & DMSO | 0.04 | 2.68 | 1.10 | 0.74 | 1429 | 39 |
The deposition methods are abbreviated as BC (blade coating) and DC (drop casting). The birefringence Δn = ne – no is given at an energy of 2.5 eV as an indication of the optical anisotropy of each film. The Drude parameters correspond to the ordinary component.