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. 2022 Oct 18;7(43):39429–39436. doi: 10.1021/acsomega.2c05945

Table 1. Parameters Determined from Ellipsometry and Raman Spectra for Selected Samples Studied in This Worka.

deposition Δn(2.5 eV) ε Ep(eV) Γp(eV) ω (cm–1) Δω (cm–1)
PEDOT:PSS Sigma-Aldrich 483095 (1:1.6 ratio by weight)
BC 0.20 2.68 1.28 0.51 1422 41
DC 0.36 2.78 1.48 0.70 1422 41
DC & DMSO 0.15 2.59 1.67 0.82 1427 41
PEDOT:PSS Heraeus Clevios AI4083 (1:6 ratio by weight)
BC 0.01 2.52 1.27 0.67 1437 44
BC 0.12 2.58 1.03 0.72 1432 42
DC 0.12 2.56 1.01 0.74 1431 43
DC & DMSO 0.04 2.68 1.10 0.74 1429 39
a

The deposition methods are abbreviated as BC (blade coating) and DC (drop casting). The birefringence Δn = neno is given at an energy of 2.5 eV as an indication of the optical anisotropy of each film. The Drude parameters correspond to the ordinary component.