Table 2.
YS | OS | OC | RC | |
---|---|---|---|---|
λPL (nm) | 583 | 598 | 603 | 613 |
ΦPL | 0.148 | 0.154 | 0.281 | 0.205 |
τp (ns) | 60.36 (100%) | 61.42 (13.65%) | 5.80 (12.27%) | 10.00 (30.18%) |
τd (μs) | / | 0.34 (86.35%) | 0.35 (87.73%) | 0.15 (69.82%) |
kr (107 s−1) | 0.25 | 0.25 | 4.84 | 2.05 |
knr (107 s−1) | 1.41 | 1.38 | 12.40 | 7.95 |
S1 (eV) | 2.05 (1LE) | 2.03 (1CT) | 2.23 (1CT) | 2.24 (1CT) |
T1 (eV) | 1.72 (3LE) | 1.81 (3LE) | 2.15 (3CT) | 2.20 (3CT) |
ΔEST (eV) | 0.33 | 0.22 | 0.08 | 0.04 |