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. 2022 Oct 24;126(43):18536–18549. doi: 10.1021/acs.jpcc.2c05927

Table 2. Gas-Phase Thiophene HDS Reaction Rates and Liquid-Phase Dibenzothiophene HDS Reaction Rate Constants of A (Sulfide) and B (Sulfide).

  thiophene
DBT
gas-oil
  selectivity  
catalyst reaction rates (mol molMo–1 h–1) conversion (%) reaction temperature (°C) conversion (%) BP CHB reaction rate constants (mol molMo–1 h–1) reaction rate constants (mol molMo–1 h–1)
A (sulfide) 53.4 ± 0.8 46.1 230 7.6 90.0 10.0 3.4 4.96
250 16.7 83.8 16.2 7.8
270 34.1 75.6 24.4 17.7
B (sulfide) 101.9 ± 0.8 87.2 230 25.4 57.8 42.2 12.5 22.31
250 51.3 54.3 45.7 30.6
270 85.2 50.7 49.3 81.2