Table 2. Gas-Phase Thiophene HDS Reaction Rates and Liquid-Phase Dibenzothiophene HDS Reaction Rate Constants of A (Sulfide) and B (Sulfide).
| thiophene |
DBT |
gas-oil | ||||||
|---|---|---|---|---|---|---|---|---|
| selectivity | ||||||||
| catalyst | reaction rates (mol molMo–1 h–1) | conversion (%) | reaction temperature (°C) | conversion (%) | BP | CHB | reaction rate constants (mol molMo–1 h–1) | reaction rate constants (mol molMo–1 h–1) |
| A (sulfide) | 53.4 ± 0.8 | 46.1 | 230 | 7.6 | 90.0 | 10.0 | 3.4 | 4.96 |
| 250 | 16.7 | 83.8 | 16.2 | 7.8 | ||||
| 270 | 34.1 | 75.6 | 24.4 | 17.7 | ||||
| B (sulfide) | 101.9 ± 0.8 | 87.2 | 230 | 25.4 | 57.8 | 42.2 | 12.5 | 22.31 |
| 250 | 51.3 | 54.3 | 45.7 | 30.6 | ||||
| 270 | 85.2 | 50.7 | 49.3 | 81.2 | ||||