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UV–vis spectroelectrochemistry of [Fe(brphtmeimb)2]PF6 (red line) in acetonitrile (0.1-M N(n-butyl)4PF6). Left: Reduction at −1.44 V generating [Fe(brphtmeimb)2] (blue line). Right: Oxidation at 0.76 V generating [Fe(brphtmeimb)2]2+ (blue line).
