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. 2022 Oct 24;61(44):17515–17526. doi: 10.1021/acs.inorgchem.2c02410

Table 2. Steady State Photophysical Properties Including the Absorption Maximum (Abs max), Its Full Width at Half-Maximum (FWHM), the Peak Extinction Coefficient (ε), the Emission Maximum (Em max), Its FWHM, the Emission Quantum Yield (ϕ), and Finally the 0–0 Energy (E00) of All Complexes Discussed in This Report.

Substituent Abs maxa(nm/eV) Abs fwhm (eV) Ext coeffε (M–1 cm–1) Em maxa(nm/eV) Em fwhm (eV) ϕ (%) Ε00 (eV)
[Fe(phtmeimb)2]PF6b 502/2.47 0.58 3000 655/1.89 0.43 2.1 2.14
[Fe(brphtmeimb)2]PF6 508/2.44 0.60 3500 658/1.88 0.43 1.8 2.13
[Fe(meophtmeimb)2]PF6 503/2.74 0.59 3600 658/1.88 0.43 1.7 2.13
[Fe(coohphtmeimb)2]PF6 505/2.46 0.58 3100 661/1.88 0.43 1.9 2.14
a

Defined as where the derivative of the spectrum with respect to wavelength is zero.

b

Data from ref (23).