Table 2. Steady State Photophysical Properties Including the Absorption Maximum (Abs max), Its Full Width at Half-Maximum (FWHM), the Peak Extinction Coefficient (ε), the Emission Maximum (Em max), Its FWHM, the Emission Quantum Yield (ϕ), and Finally the 0–0 Energy (E00) of All Complexes Discussed in This Report.
Substituent | Abs maxa(nm/eV) | Abs fwhm (eV) | Ext coeffε (M–1 cm–1) | Em maxa(nm/eV) | Em fwhm (eV) | ϕ (%) | Ε00 (eV) |
---|---|---|---|---|---|---|---|
[Fe(phtmeimb)2]PF6b | 502/2.47 | 0.58 | 3000 | 655/1.89 | 0.43 | 2.1 | 2.14 |
[Fe(brphtmeimb)2]PF6 | 508/2.44 | 0.60 | 3500 | 658/1.88 | 0.43 | 1.8 | 2.13 |
[Fe(meophtmeimb)2]PF6 | 503/2.74 | 0.59 | 3600 | 658/1.88 | 0.43 | 1.7 | 2.13 |
[Fe(coohphtmeimb)2]PF6 | 505/2.46 | 0.58 | 3100 | 661/1.88 | 0.43 | 1.9 | 2.14 |
Defined as where the derivative of the spectrum with respect to wavelength is zero.
Data from ref (23).