. 2022 Nov 3;14(21):4706. doi: 10.3390/polym14214706

Table 1.

Summary of the more significant catalytic molecular reactions achieved using hybrid materials prepared from metallic NPs and porous polymeric supports.

Monomer/ Polymer Nature	Porogen Nature	Metal Nature	Metallic NP Preparation Strategy	NP Size (nm)	Catalytic Reaction Investigated	References
Starch	No porogen	Pd	in situ	4 (EtOH) and 2.5 (acetone)	Mizoroki–Heck coupling	[40]
					Sonogashira coupling
					Suzuki–Miyaura coupling
1,3,5-Triethynylbenzene and 1,4-dibromobenzene	No porogen	Pd	in situ	nd ^a	Suzuki–Miyaura coupling	[41]
Heptazine and piperazine	No porogen	Pd	in situ	3−5	Suzuki–Miyaura coupling	[42,43]
DSDMA	Porogenic solvent	Au	in situ	200	Eosin Y reduction	[44]
HEMA	Porogenic solvent + NaCl particle	Au	in situ	100–150	Nitroarene reduction	[45,46]
P(S-co-VBC)	Emulsion templating	Pd	in situ	2, 2.5 and 2.7	Suzuki–Miyaura coupling	[28]
P(S-co-VBC)	Emulsion templating	Pd	in situ	12.1 to 13.8	Alkene hydrogenation	[47]
HEMA	Emulsion templating	Au	in situ	Large distribution	Nitroarene reduction	[48]
HEMA	Emulsion templating	Au	in situ	Large distribution	Eosin Y reduction	[48]
PS	Emulsion templating	Au	in situ	50–200	Eosin Y reduction	[49]
PS	Porogenic solvent	Au	in situ	7–25	Nitroarene and herbicidereduction	[50]
PS	Porogenic solvent	Ag	in situ	15–25	Methylene Blue reduction	[51]
NCESB	nd ^a	Pd	in situ	5–23	Suzuki coupling	[52]
HPTPy	Porogenic solvent	Pd	in situ	9	Suzuki–Miyaura coupling	[53]
HPTPy	Porogenic solvent	Pd	in situ	9	Mizoroki–Heck coupling	[53]
PS	Sacrificial block etching	Au	in situ	nd ^a	Nitroarene reduction	[54]
PS	Sacrificial block etching	Au	in situ	100	Nitroarene reduction	[55]
PS	Sacrificial block etching	Au	in situ	100	Boronic homocoupling	[55]
NAS	Porogenic solvent	Au	in situ	nd ^a	Nitroarene reduction	[56,57]
NAS	Porogenic solvent	Au	ex situ	20	Nitroarene reduction	[56,57]
NAS	Porogenic solvent	Au	ex situ	5, 20 and 100	Nitroarene reduction	[58]
NAS	Porogenic solvent	Cu	in situ	39 ± 8	Nitroarene reduction	[59]
NAS	Porogenic solvent	Cu	ex situ	68 ± 16	Nitroarene reduction	[59]
GCMA	Porogenic solvent	Pt	in situ	nd ^a	Nitroarene reduction	[60]
PES	nd ^a	Pd	in situ	2–5, 4.7–8.4 and 6–13	Nitroarene reduction	[61,62]
				5.5 ± 1.8 and ca. 2	Alkene hydrogenation	[63,64]
				2 ± 1, 1–6, 2–5 and 6–13	Suzuki–Miyaura coupling	[27,62,65]
Cellulose triacetate	Porogenic solvent	Au	in situ	36.7 (PIMs) 2.9 (PNMs)	Nitroarene reduction	[66]
Cellulose acetate	Porogenic solvent	Pd	in situ	2.7 ± 0.4	Suzuki–Miyaura coupling	[67]

^a not defined in the article.