Table 4.
Comparison of the Ea and recyclability for the hydrolysis of amine borane compounds a.
| Entry | Catalyst | Amine Borane Compound | Ea (kJ/mol) | Recyclability Runs |
Ref. |
|---|---|---|---|---|---|
| 1 | CoRh@PVP nanoclusters | AB | 42.7 | 5 | [40] |
| 2 | NiCo alloy on N-doped carbon | AB | 43.6 | 6 | [41] |
| 3 | Co-Mo-B on Ni foam | AB | 43.6 | - | [1] |
| 4 | Pd0/CeO2 | AB | 68.00 | 5 | [42] |
| 5 | Ru(0) nanoparticles | AB | 69.00 | 5 | [43] |
| 6 | Ru/C | AB | 76.00 | - | [44] |
| 7 | Ni in p(AAc-co-VI) | EDAB | 47.48 | - | [45] |
| 8 | Pd@p(SPA) | EDAB | 67.79 | 10 | [46] |
| 9 | Pd/C | DMAB | - | - | [47] |
| 10 | Ni-hydrogel | DMAB | 50.96 | 8 | [29] |
| 11 | Pt-Ni on carbon | DMAB | 39.79 | 5 | [39] |
| 12 | Co/MoS2 | DMAB | 58.31 | 5 | [48] |
| 13 | RhCo nanoclusters | DMAB | 50.3 | 5 | [49] |
| 14 | Ru(0) nanoparticles | DMAB | 92.4 | - | [50] |
| 15 | Pd/porous carbon | DMAB | 60.4 | 5 | [38] |
| 16 | Ni/Pd in hydrogel | DMAB | 34.95 | 20 | This work |
a Note that data about dehydrogenation in organic solvents are not listed here. AB: ammonia borane; EDAB: ethylenediamine bisborane; DMAB: dimethylamine borane.