Table 5.

Reaction set used in the simulation of the chemical and biological stages for the radiolysis in water [63,66] and associated rate constants.

Reactions in Water
No.	Reaction	k (M−1 s−1)	Reference
1	eaq− + eaq− → H2 + 2OH−	6.47 × 109	[63]
2	H• + H• → H2	5.03 × 109	[63]
3	•OH + •OH → H2O2	4.75 × 109	[63]
4	eaq− + H• → H2 + OH−	2.65 × 1010	[63]
5	eaq− + •OH → OH−	2.95 × 1010	[63]
6	H• + •OH → H2O	1.44 × 1010	[63]
7	eaq−+ H2O2 → •OH + OH−	1.41 × 1010	[63]
8	eaq− + O2 → O2−	1.90 × 1010	[63]
9	eaq− + O2− → OH− + HO2−	1.30 × 1010	[63]
10	eaq− + HO2•→ HO2−	2.00 × 1010	[63]
11	H• + H2O2 → •OH + H2O	0.01 × 1010	[63]
12	H• + O2 → HO2•	2.00 × 1010	[63]
13	H• + HO2•→ H2O2	2.00 × 1010	[63]
14	H• + O2− → HO2−	2.00 × 1010	[63]
15	•OH + H2O2 → HO2•+ H2O	2.30 × 1007	[63]
16	•OH + O2− → O2 + OH−	9.00 × 1009	[63]
17	•OH + HO2• → O2 + H2O	1.00 × 1010	[63]
18	HO2• + HO2• → H2O2 + O2	7.60 × 105	[63]
19	HO2• + O2− → H2O2 + O2 + OH−	1.14 × 108	[66]
20	H+ + OH− → H2O	1.00 × 1011	[63]
21	H2O → H+ + OH−	1.29 × 10−5	[66]
22	H+ + HO2− → H2O2	2.00 × 1010	[63]
23	H2O2 → H+ + HO2−	6.49 × 10−2	[66]
24	H2O2 + OH− → HO2−+ H2O	1.18 × 1010	[66]
25	HO2−+ H2O → H2O2 + OH−	9.97 × 105	[66]
26	•OH → H+ + O−	6.49 × 10−2	[66]
27	H+ + O− → •OH	4.52 × 1010	[66]
28	•OH + OH− → O− + H2O	1.18 × 1010	[66]
29	O− + H2O → •OH + OH−	9.97 × 105	[66]
30	HO2•→ H+ + O2−	6.62 × 105	[66]
31	H+ + O2− → HO2•	3.00 × 1010	[63]
32	HO2•+ OH− → O2− + H2O	9.78 × 10−2	[66]
33	O2− + H2O → HO2• + OH−	1.18 × 1010	[66]
34	H+ + e−aq → H•	2.11 × 1010	[63]
35	H• → H+ + e−aq	3.7	[66]
36	H• + OH−→ e−aq+ H2O	2.00 × 107	[63]
37	e−aq+ H2O → H• + OH−	1.23 × 101	[66]
38	H• + H2O → H2 + •OH	2.26 × 10−5	[66]
39	H2 + •OH → H• + H2O	4.50 × 107	[63]