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. 2022 Nov 6;11(21):3533. doi: 10.3390/foods11213533

Table 2.

Identified chemical components of Yarrow (Achillea millefolium L.) essential oil.

No Retention Time (min) KI a KI b Identified Compounds Area c (%)
1 9.425 957 952 α-Pinene 1.49
2 9.746 963 953 Camphene 2.97
3 10.145 985 976 Sabinene 0.53
4 10.294 991 980 β-Pinene 0.97
5 11.117 1028 1026 p-Cymene 0.89
6 11.225 1033 1031 β-Ocimene 1.75
7 11.413 1042 1039 Eucalyptol 17.07
8 12.762 1102 1098 Linalool 3.57
9 12.904 1109 1110 α-Thujone 12.10
10 13.005 1114 1115 Cyclooctanone 1.60
11 13.078 1117 1115 β-Thujone 3.81
12 13.250 1126 1138 cis-Limonene oxide 1.44
13 13.779 1151 1143 Camphor 18.55
14 13.975 1160 1162 Pinocarvone 1.63
15 14.062 1164 1169 Lavandulol 1.14
16 14.249 1173 1165 Borneol 3.78
17 14.647 1192 1189 α-Terpineol 7.23
18 14.772 1198 1202 Myrtenol 0.51
19 15.471 1231 1242 Carvone 0.64
20 16.199 1269 1256 Neral (β-citral) 1.95
21 16.496 1284 1274 Geranial (α-citral) 2.51
22 16.755 1297 1294 Limonene dioxide 2.40
23 20.390 1493 1383 Geranyl acetate 1.65
24 22.069 1601 1583 Caryophyllene oxide 0.51
25 22.206 1609 1575 Spathulenol 0.79
26 22.814 1684 1525 1-Naphthalenol 1.23
27 23.181 1734 1652 α-Eudesmol 0.82
Total identified compounds (%) 94.65

A DB-5 column (polydimethylsiloxane, dimensions: 60 m × 0.25 mm), a flame-ionized detector operating at electron ionization mode at 70 eV, and carrier gas of helium at a flow rate of 1.2 mL/min were used for the characterization of GC-MS components. The compounds are listed in order of their retention time on the DB-5 column. KI a: Experimental Kovats indices calculated from the GC-MS chromatogram. KI b: Kovats indices matching with those of published literature (NIST, Wiley). c Relative percentages of constituents using peak area normalization. (i.e., the peak areas for solvent compounds appeared earlier than the lowest number of n-alkanes (e.g., RT of 9.425 in this study) were discarded and the area of individual peaks was normalized).