Table 2.
No | Retention Time (min) | KI a | KI b | Identified Compounds | Area c (%) |
---|---|---|---|---|---|
1 | 9.425 | 957 | 952 | α-Pinene | 1.49 |
2 | 9.746 | 963 | 953 | Camphene | 2.97 |
3 | 10.145 | 985 | 976 | Sabinene | 0.53 |
4 | 10.294 | 991 | 980 | β-Pinene | 0.97 |
5 | 11.117 | 1028 | 1026 | p-Cymene | 0.89 |
6 | 11.225 | 1033 | 1031 | β-Ocimene | 1.75 |
7 | 11.413 | 1042 | 1039 | Eucalyptol | 17.07 |
8 | 12.762 | 1102 | 1098 | Linalool | 3.57 |
9 | 12.904 | 1109 | 1110 | α-Thujone | 12.10 |
10 | 13.005 | 1114 | 1115 | Cyclooctanone | 1.60 |
11 | 13.078 | 1117 | 1115 | β-Thujone | 3.81 |
12 | 13.250 | 1126 | 1138 | cis-Limonene oxide | 1.44 |
13 | 13.779 | 1151 | 1143 | Camphor | 18.55 |
14 | 13.975 | 1160 | 1162 | Pinocarvone | 1.63 |
15 | 14.062 | 1164 | 1169 | Lavandulol | 1.14 |
16 | 14.249 | 1173 | 1165 | Borneol | 3.78 |
17 | 14.647 | 1192 | 1189 | α-Terpineol | 7.23 |
18 | 14.772 | 1198 | 1202 | Myrtenol | 0.51 |
19 | 15.471 | 1231 | 1242 | Carvone | 0.64 |
20 | 16.199 | 1269 | 1256 | Neral (β-citral) | 1.95 |
21 | 16.496 | 1284 | 1274 | Geranial (α-citral) | 2.51 |
22 | 16.755 | 1297 | 1294 | Limonene dioxide | 2.40 |
23 | 20.390 | 1493 | 1383 | Geranyl acetate | 1.65 |
24 | 22.069 | 1601 | 1583 | Caryophyllene oxide | 0.51 |
25 | 22.206 | 1609 | 1575 | Spathulenol | 0.79 |
26 | 22.814 | 1684 | 1525 | 1-Naphthalenol | 1.23 |
27 | 23.181 | 1734 | 1652 | α-Eudesmol | 0.82 |
Total identified compounds (%) | 94.65 |
A DB-5 column (polydimethylsiloxane, dimensions: 60 m × 0.25 mm), a flame-ionized detector operating at electron ionization mode at 70 eV, and carrier gas of helium at a flow rate of 1.2 mL/min were used for the characterization of GC-MS components. The compounds are listed in order of their retention time on the DB-5 column. KI a: Experimental Kovats indices calculated from the GC-MS chromatogram. KI b: Kovats indices matching with those of published literature (NIST, Wiley). c Relative percentages of constituents using peak area normalization. (i.e., the peak areas for solvent compounds appeared earlier than the lowest number of n-alkanes (e.g., RT of 9.425 in this study) were discarded and the area of individual peaks was normalized).