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. 2022 Nov 16;12(51):32853–32884. doi: 10.1039/d2ra06303d

Crystallographic properties of Cu2O and CuO41.

Parameters Cu2O CuO
Structure: Cu(i)-yellowish, Cu(ii)-greyish black, O-red graphic file with name d2ra06303d-u1.jpg graphic file with name d2ra06303d-u2.jpg
Unit cell a = b = c = 4.26 Å a = 4.6837 Å, b = 3.4226 Å, c = 5.1288 Å
α = β = γ = 90° α, γ = 90°, β = 99.54°
Space group Pnm (224) C2/c (15)
Bond length, Å Cu–O 1.849 1.96
O–O 3.68 2.62
Cu–Cu 3.012 2.90
Cell volume, Å3 77.83 81.08
Formula weight 143.14 79.57
Density, g cm−3 5.749–6.140 6.515
Melting point, °C 1235 1201