Crystallographic properties of Cu2O and CuO41.
| Parameters | Cu2O | CuO | |
|---|---|---|---|
| Structure: Cu(i)-yellowish, Cu(ii)-greyish black, O-red |
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| Unit cell | a = b = c = 4.26 Å | a = 4.6837 Å, b = 3.4226 Å, c = 5.1288 Å | |
| α = β = γ = 90° | α, γ = 90°, β = 99.54° | ||
| Space group | Pn3̄m (224) | C2/c (15) | |
| Bond length, Å | Cu–O | 1.849 | 1.96 |
| O–O | 3.68 | 2.62 | |
| Cu–Cu | 3.012 | 2.90 | |
| Cell volume, Å3 | 77.83 | 81.08 | |
| Formula weight | 143.14 | 79.57 | |
| Density, g cm−3 | 5.749–6.140 | 6.515 | |
| Melting point, °C | 1235 | 1201 | |