| FTO/c-TiO2/CsPbIBr2 (@250 °C)/Au |
Dual source evaporation |
0.159 |
4.7 |
8.7 |
0.959 |
56 |
— |
2016 (ref. 33) |
| FTO/bl-TiO2/mp-TiO2/CsPbIBr2 (@300 °C)/Spiro-OMeTAD/Au |
Spray assisted two-step solution |
0.159 |
6.3 |
7.8 |
1.127 |
72 |
— |
2016 (ref. 98) |
| FTO/In2S3/CsPbIBr2 (@160 °C)/Spiro-OMeTAD/Ag |
Spin-coating |
0.11 |
5.59 |
7.76 |
1.09 |
65.94 |
— |
2019 (ref. 100) |
| FTO/c-TiO2/CsPbIBr2 (@320 °C)/Spiro-OMeTAD/Au |
A gas-assisted method |
0.16 |
8.02 |
9.69 |
1.227 |
67.4 |
— |
2017 (ref. 99) |
| FTO/NiOx/CsPbIBr2 (@160 °C)/MoOx/Au |
One-step solution |
0.09 |
5.52 |
10.56 |
0.85 |
62 |
— |
2017 (ref. 101) |
| FTO/NiOx/CsPbIBr2 (@160 °C)/ZnO/Al |
Single-step method |
0.04 |
5.08 |
8.53 |
0.97 |
61.4 |
— |
2018 (ref. 118) |
| ITO/SnO2/CsPbIBr2 (@100 °C)/Spiro-OMeTAD/Au |
Spin-coating (CB anti-solvent) |
0.16 |
9.5 |
11.52 |
1.19 |
69 |
— |
2018 (ref. 119) |
| FTO/c-TiO2/m-TiO2/CsPbIBr2 (@350 °C)/carbon |
Two-step solution |
0.09 |
7.36 |
13.15 |
0.99 |
57 |
Decreased by 8% of initial PCE value |
2018 (ref. 111) |
| FTO/c-TiO2/m-TiO2/CsPb0.9Sn0.1IBr2 (@350 °C)/carbon |
Two-step sequential solution-phase process |
0.09 |
11.33 |
14.30 |
1.26 |
63 |
The encapsulated PSCs exhibited almost no degradation after being kept for >3 months at RT |
2017 (ref. 110) |
| ITO/SnO2/C60/CsPb0.75Sn0.25IBr2 (@150 °C)/Spiro-OMeTAD/Au |
Spin-coating (CB anti-solvent) |
0.10 |
11.53 |
12.57 |
1.21 |
75.8 |
Maintained over 90% of the initial PCE after 120 min illumination without encapsulation |
2018 (ref. 102) |
| ITO/SnO2/CsPb0.7Sn0.3IBr2 (@160 °C)/Spiro-OMeTAD/Au |
One-step spin-coating |
0.06 |
14.1 |
15.5 |
1.18 |
76.7 |
Retained over 75% of original PCE after 10 days exposure to air |
2022 (ref. 120) |
| FTO/c-TiO2/CsPbIBr2 (@100 °C)/carbon |
One-step spin-coating |
0.09 |
6.55 |
9.11 |
1.142 |
63 |
Retained 95% initial efficiency after 288 h of storage |
2018 (ref. 103) |
| ITO/NH4Cl–ZnO/CsPbIBr2 (@160 °C)/Spiro-OMeTAD/Ag |
One-step spin-coating |
0.11 |
10.16 |
11.52 |
1.27 |
69.17 |
Remained almost 70% of the initial value after storage for 800 h in a cabinet (RH: 15%, T: 25 °C) |
2020 (ref. 106) |
| FTO/SnO2/Cs0.99MA0.01PbIBr2 (@150 °C)/Spiro-OMeTAD/Au |
One-step spin-coating |
0.06 |
10.47 |
11.94 |
1.21 |
72.5 |
Retained 84% of initial PCE after 30 days |
2020 (ref. 104) |
| ITO/c-TiO2/CsPbIBr2 (@160 °C)/carbon |
One-step spin-coating (Zn(Ac)2-doped) |
0.12 |
10.65 |
11.80 |
1.291 |
70 |
Maintained 95% of starting PCE value after 30 days with continuous aging |
2022 (ref. 121) |
| ITO/SnO2/MgO/CsPbIBr2 (@160 °C)/Spiro-OMeTAD/Ag |
One-step spin-coating |
0.11 |
11.04 |
11.70 |
1.36 |
69.35 |
— |
2020 (ref. 107) |
| FTO/c-TiO2/CsPbIBr2 (@160 °C)/Spiro-OMeTAD/Au |
One-step spin-coating |
0.09 |
10.78 |
11.63 |
1.25 |
74 |
— |
2020 (ref. 105) |
| FTO/c-TiO2/Li–CsPbIBr2 (@280 °C)/CuPc/carbon |
One-step spin-coating |
0.071 |
9.25 |
10.27 |
1.22 |
74 |
Maintained 96% of initial PCE after being exposed to air with RH of 40% at 60 °C for one month |
2019 (ref. 112) |
| FTO/c-TiO2/CsPbIBr2 (@160 °C)/carbon |
One-step spin-coating |
0.09 |
9.04 |
10.87 |
1.26 |
66 |
Maintained 95% of initial PCE after 7d storage |
2020 (ref. 113) |
| FTO/c-TiO2/Rb or Ac co-doped CsPbIBr2 (@250 °C)/carbon |
One-step spin-coating |
0.09 |
10.78 |
11.74 |
1.37 |
67 |
Retained 98% of initial PCE after storage for 7 days |
2021 (ref. 114) |
| FTO/c-TiO2/CsI(PbBr2)0.95(CoCl2)0.05 (@250 °C)/Spiro-OMeTAD/Ag |
One-step spin-coating |
0.07 |
10.43 |
12.48 |
1.25 |
66.88 |
Maintained above 90% of initial PCE for 25 days in the air at 25 °C and RH = 20% without encapsulation |
2020 (ref. 115) |
| FTO/c-TiO2/CsPb0.99Zn0.01IBr2 (@250 °C)/Spiro-OMeTAD/Ag |
One-step spin-coating |
0.07 |
10.51 |
11.92 |
1.28 |
69 |
Maintained 91% of initial PCE after 30 days without encapsulation and stored at 25 °C under ambient conditions with RH of 20% |
2021 (ref. 117) |
| FTO/c-TiO2/CsPbIBr2-0.50% Cu (@225 °C)/Spiro-OMeTAD/Ag |
One-step spin-coating |
0.0625 |
10.4 |
12.8 |
1.21 |
67.1 |
Retained almost 75% of initial PCE when heated at 90 °C in ambient atmosphere with 30% humidity |
2020 (ref. 116) |
| ITO/ZnO/CsPbIBr2 (@140 °C)/Spiro-OMeTAD/Au |
One-step spin-coating (vacuum-assisted low-temperature engineering) |
0.04 |
11.01 |
11.34 |
1.289 |
75.31 |
Retained over 87% of initial PCE after being continuously heated at 80 °C in an inert atmosphere for 80 days without encapsulation |
2022 (ref. 122) |
| FTO/c-TiO2/CsPbIBr2 (@150 °C)/ZnPc/carbon |
Two-step spin-coating (CB and IPA mixed anti-solvent) |
0.09 |
8.48 |
10.33 |
1.23 |
66.9 |
Retained about 90% of initial efficiency after storage at 20% RH in air for 30 days |
2022 (ref. 123) |
