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. 2022 Nov 1;61(45):18135–18146. doi: 10.1021/acs.inorgchem.2c02807

Table 3. Pressure Coefficients of the Mn4+ and Cr3+ ZPL (2E → 4A2) Energies in Some Oxide Phosphors.

material activator ΔEP, meV/GPa T, K ref
α-Al2O3 Mn4+ –1.05 (R1) 300 (29)
    –1.06 (R2)    
YAlO3 (YAP)   –1.43 10 (30)
Gd3Ga5O12 (GGG)   –2.32 (site 1) 15 (31)
    –1.85 (site 2)    
Sr4Al14O25   –2.64 300 (25)
Mg2TiO4   –2.4 50 (32)
β-Ga2O3   –2.0 85 this work
α-Ga2O3   not estimated 85 this work
β-Ga2O3 Cr3+ –2.4 (R1) 85 (7)
    –0.6 (R2)    
    –2.4 (R1) 85 this work
    –1.2 (R2)    
β-Ga1.58Al0.4O3   –1.5 (R1) 300 (5)
    –1.0 (R2)    
β-Ga0.38Al1.6O3   –1.28 (R1) 300 (6)
    –1.1 (R2)    
α-Al2O3   –0.9 (R1) 300 (33)
    –1.0 (R2)    
    –0.9 (R1) 300 (34)
α-Ga1.58Al0.4O3   –1.09 300 (6)
α-Ga0.38Al1.6O3   –1.13 300 (6)