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. 2022 Nov 1;61(45):18135–18146. doi: 10.1021/acs.inorgchem.2c02807

Table 4. Parameters of Fits Obtained from the Temperature Dependence of the Emission Intensity (Equation 2) for Mn4+ Emission in (Al1–xGax)2O3.

sample composition (x value) ΔE1, meV ΔE2, meV T1/2,a K
0 148 ± 7 1029 ± 6 380
0.05 91 ± 27 727 ± 210 370
0.1 190 ± 15 666 ± 40 336
0.15 186 ± 86 657 ± 89 336
0.2 90 ± 10 416 ± 17 285
0.25 16 ± 3 272 ± 24 262
0.5 14 ± 11 285 ± 50 247
0.75 11 ± 3 142 ± 17 174
1.0   147 ± 14 114
1.0b 7 ± 2 100 ± 12 132
a

Temperature when the I(T) intensity is half of I(0).

b

α-Ga2O3:Mn4+.