Table 5.
Adsorption kinetics for adsorption of Cu (II) onto the two floating plant species.
Model | Adsorbent | Sorbent |
Parameter |
||||||
---|---|---|---|---|---|---|---|---|---|
Cu(II) Concentration (mg/L) | qe,exp (mg g−1) | qe,cal (mg g−1) | k1 (day−1) | R2 | |||||
(a) | Pseudo-first-order | Azolla filiculoides | 0.25 | 0.2297 | 0.5049 | −0.1299 | 0.3309 | ||
0.5 | 0.8912 | 0.9480 | −0.0101 | 0.3309 | |||||
0.75 | 1.1676 | 0.4305 | −0.1292 | 0.1161 | |||||
1 | 1.6819 | 0.2202 | −0.1654 | 0.0675 | |||||
Lemna minor | 0.25 | 0.2494 | 0.2121 | −0.2639 | 0.4903 | ||||
0.5 | 1.4020 | 0.6001 | 0.0226 | 0.0073 | |||||
0.75 | 2.4328 | 1.2900 | 0.0523 | 0.1014 | |||||
1 | 4.0473 | 3.8353 | 0.4470 | 0.7581 | |||||
(b) | Model | Adsorbent | Sorbent | Parameter | |||||
Cu(II) Concentration (mg/L) | qe,exp (mg g−1) | qe,cal (mg g−1) | k2 (g mg−1 day) | R2 | |||||
Pseudo-second-order | Azolla filiculoides | 0.25 | 0.230 | 0.2297 | 3.7894 × 1015 | 1 | |||
0.5 | 0.891 | 0.819 | - | 1 | |||||
0.75 | 1.168 | 1.1733 | 27.6204 | 0.9999 | |||||
1 | 1.682 | 1.6969 | 9.9506 | 0.9996 | |||||
Lemna minor | 0.25 | 0.249 | 0.2879 | 14.0513 | 0.9648 | ||||
0.5 | 1.402 | 1.0385 | −5.3286 | 0.9209 | |||||
0.75 | 2.432 | 1.5201 | −2.5817 | 0.8822 | |||||
1 | 4.047 | 4.6577 | 0.1259 | 0.8191 | |||||
(c) | Model | Adsorbent | Sorbent | Parameter | |||||
Cu(II) Concentration (mg/L) | ki (mg g−1 min−1) | I (mg g−1) | R2 | ||||||
Intra-particle diffusion | Azolla filiculoides | 0.25 | 0.077 | 0.0714 | 0.6114 | ||||
0.5 | 0.2987 | 0.2771 | 0.6114 | ||||||
0.75 | 0.4006 | 0.3319 | 0.6619 | ||||||
1 | 0.5856 | 0.4462 | 0.696 | ||||||
Lemna minor | 0.25 | 0.0843 | 0.0314 | 0.8137 | |||||
0.5 | 0.3823 | 0.2732 | 0.5774 | ||||||
0.75 | 0.6189 | 0.4506 | 0.5302 | ||||||
1 | 1.6135 | −0.0762 | 0.9455 |