PCL |
MWCNT |
3 wt % |
0.15–0.6 |
electrical |
controlled resistive heating (0.6–15.7 mA) |
60 |
130 |
1W-SM and 2W-SM
effects; RF > 96.7% and RR > 88.9%; variable electric current to achieve constant
temperature
and constant heating and cooling rates; nonlinear evolution of ρe within shape memory cycle |
(101) |
PU |
MWCNT + Fe3O4
|
30 wt % Fe3O4 +0.25–1 wt % MWCNT |
|
magnetic |
29.7 kA/m at 45
kHz |
>45 |
60 |
RR >95% |
(178) |
PU/SM-PU |
CB |
1–5 wt % |
5 × 10–2 Ω m for 5 wt %; 10–3 Ω m for 3 wt % |
electrical |
100 V |
|
25 |
2W-SM; RR 99.8% |
(179) |
PU |
MWCNT |
5 wt % |
∼1 Ω m |
electrical |
60 V |
100 |
10 |
|
(180) |
EP |
MWCNT |
0.2 wt % |
1–10 Ω
m |
electrical |
126–265 V |
200–250 |
<300 |
sequential recovery |
(102) |
EP |
MWCNT |
30 wt % |
47 Ω m |
electrical |
12 V |
>55 |
22 |
|
(98) |
EP |
rGO |
0.5 wt % |
0.025
Ω m |
electrical |
10 V |
>100 |
10 |
RF = 95% and RR = 98%; electrical recovery |
(181) |
PLA/PU |
MWCNT and
CF |
6 wt % |
|
electrical |
10 V |
>70 |
25 |
RR = 94%; negative Poisson ratio |
(182) |
PVAl |
MWCNT |
5–30 wt % |
0.52 Ω m for 30 wt
% |
electrical |
45–120 V |
>74 |
35 |
|
(183) |
PCL |
MWCNT coated Fe3O4
|
|
|
magnetic |
6.8 kA/m at 20 kHz |
T increase of 17.2 |
120 |
alignment of Fe3O4-coated MWCNT due to magnetic field 0.2 T; increase of elastic modulus by almost 100% but
reduction of max elongation |
(184) |
PCL |
MWCNT |
3 wt % |
0.05 Ω m |
electrical |
0.1 W |
∼50 |
|
analytical, numerical, and
experimental investigation |
(100) |
BR |
MWCNT and CB |
0–15 phr MWCNT or 0–30 phr CB |
10–2 Ω
m for 15 phr CNT or 30 phr CB |
electrical |
50 V |
110 after 15 min at 50 V |
900 |
lower ρe and higher RF and RR for
CNT than CB |
(87) |
PU |
Fe3O4
|
0–9 wt % |
|
magnetic |
250 A/m at 20 kHz |
>52 |
35 |
RR decrease with ς, slight RF increase with ς |
(185) |
PBS–PEG |
CNT |
0.2–1 wt
% |
7.05 Ω m
for 1 wt
% |
electrical |
20–120 V |
85 at 70 V for 1 wt % |
55 |
CNT reduced ductility |
(186) |
PU |
CNF |
1–7 wt % |
560 Ω m for 7 wt % |
electrical |
100–300 V |
25–55 |
|
χc, RF decrease
with ς of CNF; elastic modulus
increase with CNF ς |
(187) |
PU |
CNT |
3 wt % |
0.037 Ω m |
electrical |
50 V |
>40 |
40 |
different preparation techniques
and effect of dispersion and electrical properties |
(93) |
PU |
G sheet |
1–8 wt % |
1.17 Ω
m for 8 wt
% |
electrical |
65–80 V |
>70 |
8 |
2W-SM; study mechanical
properties; RF = 95%; RR = 93% |
(111) |
PU |
CNT |
4 wt % |
|
electrical |
40 V |
100 cross-linked
CNT |
50 |
CNT covalently bonded to
PU; increase RR and RF for cross-linked CNT (>10%) |
(92) |
PU |
rGO |
0–2.5 phr |
0.4 Ω m for 2.5 phr |
electrical |
50 V |
64 for 2.5 phr |
120 |
Tg and mechanical properties increase with ς; ductility increase with cycles; RR decreases with ς |
(114) |
EOC |
CB |
0–38 wt % |
0.08 Ω m for 17 wt
% |
electrical |
5–15 V for 17 wt % |
40–160 |
60 |
two different CB fillers; lower RR for higher ς |
(85) |
PU |
rGO + Fe3O4 and γ-Fe2O3
|
3 wt % GO + 7 wt % Fe3O4
|
|
magnetic |
287 kHz with 300A in coil |
70 for mixture, 60 for hybrid |
60 |
Young modulus doubled from
hybrid to only Fe3O4
|
(188) |
PU |
Ni powder chains |
0–20 vol% |
0.005–0.01 Ω m for 20%, 104 for 4% |
electrical |
6 V |
55 |
90 |
alignment magnetic field;
decrease Tg with ς |
(142) |
PU |
CB with and without 0.5
vol% Ni |
4–10% CB |
0.1 Ω m for 10% CB + chained 0.5% Ni |
electrical |
30 V |
80 |
120 |
ρe increases with number of cycles |
(189) |
PVAl |
CNT and G |
20 phr GO and 4–16 phr CNT |
0.1 Ω m for 20 GO
+ 16 CNT |
electrical |
60 V |
100 max (normally 60) |
120 |
ρe decreases
with bending angle |
(190) |
PS |
CNT |
1.47–7.02 wt % |
0.01 Ω
m for 7.02
wt % |
electrical |
35 V |
>85 |
80 |
RR ≈ 100% |
(96) |
PU |
GNP |
1–3% |
4 Ω m for 3% GNP |
electrical |
75 V |
100 for 3% |
60 |
χc, elastic modulus, RF and RR increase with ς; strength, Tg, and Tm decrease with ς |
(191) |
EP |
Ag decorated rGO and CF
mat |
2–4 wt % rGO and 11.6% CF |
2.3 × 103 Ω m |
electrical |
8.6 V |
100 |
36 |
RR = 99% |
(192) |
PS |
MWCNT nanopaper |
1.47–7.02 wt % |
0.008 Ω
m for 7.02
wt % |
electrical |
0.6 A |
>62 |
300 |
RR = 98% |
(95) |
EP |
CNF |
9.18 wt %? |
0.03 Ω m |
electrical |
10–20 V |
>50 |
2.1 |
increase elastic modulus above Tg, increase κ |
(193) |
PU |
MWCNT |
3–7 wt % |
12 Ω m for 3 wt % |
electrical |
40 V |
>70 in 10 s |
9 |
Young modulus
increase by
50%; RR > 98%; Tc increase with ς |
(194) |
PU |
Fe3O4
|
0–10 wt % |
|
magnetic |
30 kA/m
at 258 kHz |
70 at 150 s 12.5 kA/m 258 kHz |
22 |
magnetic heating depends
on geometry; for high ς, RF and RR higher for magnetic actuation |
(135) |
PK BMI |
MWCNT |
8 wt % |
∼ 0.06 Ω m |
electrical |
20–50 V |
40–140 |
|
RR = 90% by 40 V; self-healing |
(195) |
PU |
MWCNT |
3–10% |
0.9 Ω m |
electrical |
9.5 mA |
32 |
|
|
(164) |
PU |
GO |
0–20 phr |
>7 × 102 Ω m |
electrical |
100–200 V |
<60 |
|
|
(196) |
EP |
Fe3O4 coated with oelic acid |
1.5–8 wt % |
|
magnetic |
30 mT at 293 kHz |
T increase
of +25 |
60 |
|
(133) |
PPC/PLA |
MWCNT |
1–3 phr |
0.1 Ω m for 3 phr |
electrical |
20–30 V |
130 max for PPC/PLA (50/50) 3 phr at 30 V |
30 |
max tensile strength and
strain at break increased with ς at room temperature; At 50 °C strength decrease with concentration; RR = 97% |
(197) |
PLA/PU (70/30) |
CB |
0–8 phr |
∼0.4 Ω m for
8 phr |
electrical |
30 V |
98 for 8 phr |
80 |
RF = 90%; RR increase from 59%
to 85.9% for 8 phr
CB; conductivity ∼1 order of magnitude higher for PLA/PU(70/30) than for PLA |
(198) |
PU |
CF/PU yarn fabric |
10.9% CF |
1 × 10–3 Ω m |
electrical |
6 V |
87 |
80 |
RR = 99.3%; applications of deployable
structure |
(82) |
PEVA |
CNF |
0–15 wt % |
0.204 Ω m for 15 wt
%; 5 × 109 Ω
m for 3 wt % |
electrical |
60 V |
100 after 25 s |
|
2W-SM; RR decreases with ς |
(199) |
PU/PCL |
modified MWCNT |
2–10 wt % |
1 Ω
m for 10 wt %;
102 Ω m for 4 wt % |
electrical |
40 V |
>50 |
15 |
Tg of PLA increase with ς; Tgof PU decrease with ς; Tcdecrease with ς |
(200) |
PU/PVDF (90/10) |
modified MWCNT |
0–10 wt % |
50 Ω m for 10 wt %
pristine CNT; 4 Ω m for 10 wt % modified CNT |
electrical |
40 V |
T rise of +40 |
15 |
κ × 4 by adding 10 wt % MWCNT; increase 10% tensile strength and decrease 100% elongation
at break for surface-modified MWCNT than pristine; RR decrease with cycles
faster for modified than pristine CNT |
(94) |
PU |
Fe3O4
|
0–40 vol% |
106 Ω m
for 40 vol% |
magnetic |
4.4 kA/m at 50 Hz |
50 |
1200 |
electric percolation at 30 wt %; Cp decrease with ς; κ increased by 0.4 for 40 vol % |
(201) |
PEVA
and PU |
FE2O3
|
0–13.6 wt % |
|
magnetic |
15–23 kA/m |
100 for PEVA; 108 for PU |
|
|
(202) |
PDL |
Fe3O4
|
5–11 wt % |
|
magnetic |
7–30 kA/m
at 258 kHz |
100 |
180 |
decreased RF (95% to 90%) and increased RR (95% to
97%) for increased ς |
(203) |
EP |
CB |
0–10 wt % |
200 Ω m for 10 wt
% |
electrical |
3.5 W constant power |
65 |
<200 |
ρe vs ε during elongation and recovery |
(204) |
PVA |
GNP |
1.5–4.5 wt
% |
0.04 Ω m
for 4.5 wt
% |
electrical |
50–70 V |
|
2.5 |
elastic modulus increases
by 1 order of magnitude from 0 to 4.5 wt %; Tg decrease with ς |
(115) |
PU |
PPy |
8–21% |
0.105 Ω m |
electrical |
40 V |
70 |
<30 |
Tm decrease with ς |
(205) |
PCL
DMA |
Fe3O4
|
2–12 wt % |
|
magnetic |
300 kHz, 5 W |
43 |
20 |
|
(206) |
PLA/PU (50/50) |
CNT |
1–5 wt % |
0.33 Ω m for 5 wt
% |
electrical |
50 V |
50–70 |
<150 |
decrease RR (13% smaller) in 5 wt %; faster
shape recovery with electrical heating than conventional; higher RR with electrical heating
than conventional |
(207) |
EP |
MWCNT nanopaper |
40 wt % |
3 × 10–3 Ω m |
electrical |
0–6 W |
20–170 |
20 |
curing with resistive heating 105 °C after 40 s at 4.6 V; recovery at 76 °C |
(97) |
PE |
CNF |
0–11.6 vol% |
0.1 Ω m for 11.6 vol% |
electrical |
1–40 V |
100–110 |
100 |
Tc and elastic modulus increase with ς; Tm decrease with ς |
(208) |
PCL/MA (50/50) |
MWCNT |
0–10 phr |
0.0384 Ω
m |
electrical |
40 V |
>70 |
56 |
|
(90) |
PU |
GNP |
|
|
electrical |
10–30 V |
60 at 10 V |
20 |
|
(209) |
PCO/PE |
MWCNT |
8–15 vol% |
0.0105 Ω m for 10
vol% |
electrical |
150 V |
>120 after 2 min |
90 |
triple SM effect;
MWCNT
dispersed in PCO; chemical cross-linking increases ρe due to agglomeration of fillers |
(210) |
SBS/LLDPE |
CB |
0–25 wt % |
1.08 Ω m for 1 wt
% CB; 7.4 × 10–2 Ω m for 25 wt % CB |
electrical |
0–120 V |
|
60 |
elongation at break decrease
by 50% from 0 to 25 wt % CB; tensile
strength increase by >50%; recovery at 40 V |
(211) |
EP |
rGO |
|
0.0027 Ω
m |
electrical |
1–6 V |
35–240 |
5 |
bending |
(110) |
PEVA/PCL |
MWCNT |
5 wt % |
0.0205 Ω
m |
electrical |
20 V |
97 |
12 |
recovery at 30 V |
(212) |
PU |
CNT |
10 to 50 layers |
22.96 Ω m |
electrical |
40 V |
90 |
30 |
CNT layers at different
locations; RR = 100% at 40 V; localized and selective
actuation |
(99) |
EP/CE |
GNP |
0.8–2.4% |
11.3 × 10–2 Ω m for 2.4% |
electrical |
20–120 V |
|
98 |
strength increased by 25%
for 1.6 wt %; recovery at 60 V |
(213) |
EP |
Ag-CF |
5.4 wt %, 1.8 wt % |
95.1 Ω m
for 5.4 wt %; 1 × 106 Ω m for 1.8 wt % |
electrical |
60–120 V |
|
60 |
RF increase with ς; RR decrease with
ς |
(81) |
EP |
MWCNT and CB |
1.9 wt % total |
2 × 105 Ω m for 0.8 wt % MWCNT |
electrical |
225 V |
>80 |
570 |
RR = 99% |
(214) |
PLA/PU (70/30) |
MWCNT and CB |
3–5 phr CB and 0–2 phr MWCNT |
<0.1 Ω m for CB
5 phr and >1 phr MWCNT |
electrical |
30 V |
70 °C |
100 |
70 °C after 100 s for 3 phr CB and 1 phr CNT; RR = 0 |
(215) |
PPDO–PCL/PU |
Fe3O4
|
0–10 wt % |
|
magnetic |
7–30 kA/m
at 256–732 kHz |
65 |
|
|
(136) |
PMMA–PEG |
Modified Fe3O4
|
1–5 wt % |
|
magnetic |
100 kHz,
8 kW |
40.4 |
59 |
T rise 4 °C for-surface modified Fe3O4 than for pristine; RF =
90%; RR = 95% |
(216) |
PCL |
modified MWCNT |
0–9 wt % |
20 Ω
m for >7 wt % |
electrical |
50 V for 5 wt % |
70 |
120 |
decrease RR with ς |
(217) |
PCL-Py |
SWCNT |
2 wt % |
3.6 Ω
m |
electrical |
50 V |
65 |
20 |
increase RR with ς |
(104) |
MA-based thermoset |
Fe3O4
|
0–2.5 wt
% |
|
magnetic |
0.33 mT at 297 kHz |
50 |
40 |
|
(218) |
PS |
MWCNT and CB |
1
wt % MWCNT and 10–15 wt % CB |
0.03 Ω m for CB. 0.025
Ω m for CB+CNT randomly oriented. 0.0075 Ω m for CB+CNT
chained |
electrical |
25 V |
>95 |
75 |
MWCNT in chains, reduction of ρe by more than 1 order of magnitude; ρe increases with number of shape memory cycles |
(107) |
acrylate |
NdFeB and Fe3O4
|
15
vol % of each |
|
magnetic |
40 mT at 60 kHz (to heat
up Fe3O4) + 30 mT at 0.25 Hz to actuate beam |
100 (and above) in 40 s |
|
dual magnetic
field activation;
elastic modulus increases linearly with ς; RF = 95%; RR = 100% |
(141) |
PLA |
Fe3O4
|
10–40 wt
% |
|
magnetic |
30 kA/m at 268 kHz |
>60 |
>200 |
nonmonotonic evolution of RR, modulus, tensile strength, and elongation
at break with ς |
(132) |
Nafion |
Fe3O4
|
15–25% |
|
magnetic |
Power 50–100% |
internal T 50–110, surface T < 40 |
16 |
surface modification of
Fe3O4 to improve distribution |
(219) |
PCL/PU |
GNP |
0–10 wt % |
∼1 Ω m for
10 wt % |
electrical |
10–40 V |
60 for 10 wt
% at 10 V; 100 for 10 wt % at 30 V |
60 |
5ecovery within
1 min for
7 wt % at 30 V; faster heating and recovery for higher ς; Tg, χc, viscosity increase with
ς; Tmand Tc decrease with ς |
(220) |
PLA |
PPy |
|
0.028 Ω m |
electrical |
15–40 V |
120 for 40 V |
2 |
microfiber membrane
PPy
coated; worse mechanical properties with Ppy ρe depends
on polymerization time and temperature |
(221) |
PCLA |
GO |
4.86–13.29 vol % |
|
electrical |
|
|
2.5 |
RR = 100% |
(222) |
PU/EP |
G and CNT |
0.8–3 wt % CNT and 2–12 wt % graphene |
0.31
Ω m for 12 wt
% graphene |
electrical |
100 V for 8% graphene and
3%CNT |
60 |
150 |
compressive strain; densification
at ε > 70%; 2% permanent deformation
after 100 cycles |
(223) |