Computed ΔG^≠ in kcal mol⁻¹, tunneling correction (k), Γ in %, and k_Eck, k_app, k_f, and k_overall in M⁻¹ s⁻¹ of GLD + HOO˙ reactions.

Solv.	Mechanisms		ΔG≠	κ	k Eck	k app	k f a	k overall	Γ
G	FHT	N–H	15.8	570.5	9.64 × 103			8.53 × 105	1.1
		O9–H	12.0	82.3	8.43 × 105				98.9
P	FHT	N–H	18.8	2915		2.90 × 102		3.53 × 104	0.8
		O9–H	13.8	76.4		3.50 × 104			99.2
W	SET (A−)		1.6	15.3b		7.90 × 109	7.90 × 106	8.23 × 106	96.0
	FHT	N–H	17.6	4218		3.04 × 103	3.03 × 104		0.0
	(HA)	O9–H	12.8	116.5		3.30 × 105	3.30 × 105		4.0

^a k _f = f.k_app; f(A⁻) = 0.001, f(HA) = 0.999.

^bThe nuclear reorganization energy (λ, in kcal mol⁻¹).