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(a) Schematic of changes in Zn2+ solvent sheath and local hydrogen-bond network with DMF addition. (b) Binding energies among DMF, H2O and Zn2+. (c) and (d) Major configurations when DMF binds with H2O. (e) The average and maximum atomic charge of H atoms in different configurations. (f) Electron affinity calculations of different Zn2+ solvation sheath.
