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. 2022 Aug 23;20(2):861–879. doi: 10.1007/s40201-022-00827-w

Table 4.

Isotherm parameters for the adsorption of As(III) onto BFA-Fe at different temperatures

Isotherms Constants Temperatures (Kelvin, K)
283 293 303 313 323
Langmuir KL, dm3 µg−1 0.034 0.008 0.245 0.018 0.002
qm, µg g−1 109.890 144.928 13.514 217.391 553.595
R2 (dm3 linear) 0.932 0.951 0.991 0.997 0.993
R2 (Non-Linear) 0.984 0.997 0.999 0.998 0.997
HYBRID -1.885 -3.029 93.757 -0.218 -123.732
MPSD 12.153 5.025 81.154 4.092 150.113
Freundlich KF, dm3 µg−1 8.209 1.833 5.948 7.050 3.248
n 1.883 1.314 1.511 1.513 1.802
1/n 0.531 0.751 0.521 0.551 0.555
R2 (Linear) 0.891 0.984 0.952 0.953 0.955
R2 (Non-Linear) 0.944 0.992 0.981 0.981 0.978
HYBRID -1.545 -0.933 -1.571 -1.570 5.724
MPSD 19.045 13.718 17.199 18.232 20.277
Temkin B 25.475 23.579 25.139 39.938 11.857
KT, dm3 µg−1 0.275 0.152 0.323 0.253 0.394
R2 (Linear) 0.913 0.957 0.977 0.953 0.971
R2 (Non-Linear) 0.955 0.978 0.989 0.981 0.985
HYBRID -2.353 20.414 7.047 13.215 22.194
MPSD 10.855 75.181 33.357 50.847 58.844
Redilich-Peterson aR, dm3 µg−1 1.742 5.758 1.410 1.573 20.547
KR, dm3 µg−1 8.400 12.000 12.292 15.805 58.723
Β 0.559 0.255 0.415 0.394 0.450
R2 (Linear) 0.887 0.853 0.782 0.889 0.934
R2 (Non-Linear) 0.942 0.877 0.884 0.942 0.955
HYBRID 108.144 -1.001 -1.405 -1.551 2.239
MPSD 82.139 14.977 22.324 18.315 33.301