Table 4.
Isotherms | Constants | Temperatures (Kelvin, K) | ||||
---|---|---|---|---|---|---|
283 | 293 | 303 | 313 | 323 | ||
Langmuir | KL, dm3 µg−1 | 0.034 | 0.008 | 0.245 | 0.018 | 0.002 |
qm, µg g−1 | 109.890 | 144.928 | 13.514 | 217.391 | 553.595 | |
R2 (dm3 linear) | 0.932 | 0.951 | 0.991 | 0.997 | 0.993 | |
R2 (Non-Linear) | 0.984 | 0.997 | 0.999 | 0.998 | 0.997 | |
HYBRID | -1.885 | -3.029 | 93.757 | -0.218 | -123.732 | |
MPSD | 12.153 | 5.025 | 81.154 | 4.092 | 150.113 | |
Freundlich | KF, dm3 µg−1 | 8.209 | 1.833 | 5.948 | 7.050 | 3.248 |
n | 1.883 | 1.314 | 1.511 | 1.513 | 1.802 | |
1/n | 0.531 | 0.751 | 0.521 | 0.551 | 0.555 | |
R2 (Linear) | 0.891 | 0.984 | 0.952 | 0.953 | 0.955 | |
R2 (Non-Linear) | 0.944 | 0.992 | 0.981 | 0.981 | 0.978 | |
HYBRID | -1.545 | -0.933 | -1.571 | -1.570 | 5.724 | |
MPSD | 19.045 | 13.718 | 17.199 | 18.232 | 20.277 | |
Temkin | B | 25.475 | 23.579 | 25.139 | 39.938 | 11.857 |
KT, dm3 µg−1 | 0.275 | 0.152 | 0.323 | 0.253 | 0.394 | |
R2 (Linear) | 0.913 | 0.957 | 0.977 | 0.953 | 0.971 | |
R2 (Non-Linear) | 0.955 | 0.978 | 0.989 | 0.981 | 0.985 | |
HYBRID | -2.353 | 20.414 | 7.047 | 13.215 | 22.194 | |
MPSD | 10.855 | 75.181 | 33.357 | 50.847 | 58.844 | |
Redilich-Peterson | aR, dm3 µg−1 | 1.742 | 5.758 | 1.410 | 1.573 | 20.547 |
KR, dm3 µg−1 | 8.400 | 12.000 | 12.292 | 15.805 | 58.723 | |
Β | 0.559 | 0.255 | 0.415 | 0.394 | 0.450 | |
R2 (Linear) | 0.887 | 0.853 | 0.782 | 0.889 | 0.934 | |
R2 (Non-Linear) | 0.942 | 0.877 | 0.884 | 0.942 | 0.955 | |
HYBRID | 108.144 | -1.001 | -1.405 | -1.551 | 2.239 | |
MPSD | 82.139 | 14.977 | 22.324 | 18.315 | 33.301 |