Table 5.
Isotherms | Constants | Temperatures (Kelvin, K) | ||||
---|---|---|---|---|---|---|
283 | 293 | 303 | 313 | 323 | ||
Langmuir | KL, dm3 µg−1 | 0.005 | 0.007 | 0.011 | 0.014 | 0.011 |
qm, µg g−1 | 555.555 | 133.333 | 357.143 | 81.957 | 115.279 | |
R2 (Linear) | 0.701 | 0.904 | 0.845 | 0.978 | 0.872 | |
R2 (Non-Linear) | 0.837 | 0.951 | 0.921 | 0.989 | 0.934 | |
HYBRID | -53.388 | 58.381 | -2.371 | 4.148 | 5.250 | |
MPSD | 47.282 | 50.771 | 19.200 | 15.785 | 28.029 | |
Freundlich | KF, dm3 µg−1 | 2.121 | 3.255 | 4.495 | 2.527 | 2.940 |
n | 1.059 | 1.405 | 1.172 | 1.504 | 1.542 | |
1/n | 0.935 | 0.712 | 0.853 | 0.524 | 0.548 | |
R2 (Linear) | 0.987 | 0.981 | 0.955 | 0.987 | 0.995 | |
R2 (Non-Linear) | 0.993 | 0.980 | 0.978 | 0.994 | 0.993 | |
HYBRID | -0.884 | -0.928 | -3.721 | -0.905 | 3.138 | |
MPSD | 12.378 | 13.595 | 27.511 | 11.772 | 23.757 | |
Temkin | B | 45.278 | 22.252 | 48.904 | 13.810 | 15.800 |
KT, dm3 µg−1 | 0.154 | 0.271 | 0.314 | 0.305 | 0.280 | |
R2 (Linear) | 0.908 | 0.889 | 0.945 | 0.919 | 0.833 | |
R2 (Non-Linear) | 0.953 | 0.943 | 0.973 | 0.959 | 0.913 | |
HYBRID | 25.703 | 15.775 | 53.709 | -385.128 | 25.534 | |
MPSD | 80.909 | 85.552 | 170.095 | 485.235 | 83.789 | |
Redilich-Peterson | aR, dm3 µg−1 | 20.359 | 0.851 | 3.020 | 11.830 | 251.548 |
KR, dm3 µg−1 | 45.233 | 5.375 | 15.745 | 31.712 | 759.723 | |
Β | 0.057 | 0.911 | 0.138 | 0.385 | 0.352 | |
R2 (Linear) | 0.251 | 0.757 | 0.254 | 0.958 | 0.998 | |
R2 (Non-Linear) | 0.990 | 0.984 | 0.994 | 0.990 | 0.999 | |
HYBRID | -0.737 | -0.402 | -8.184 | -0.755 | 4.014 | |
MPSD | 13.780 | 20.392 | 32.584 | 12.771 | 20.559 |