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. 2022 Nov 4;10:1035902. doi: 10.3389/fchem.2022.1035902

TABLE 2.

Bond lengths (Å) at the reaction center in the A2 section of the TDMAZ reaction on the hydroxylated surface.

Species O–H Zr–N Zr–O H–N
Im1 A2−a 0.970 2.119 2.463 2.283
TS A2−a 1.065 2.236 2.360 1.541
Im2 A2−a 3.102 2.470 2.021 1.019
Im1 A2−b 0.966 2.104 2.435 2.328
TS A2−b 1.030 2.208 2.406 1.633
Im2 A2−b 3.159 2.465 2.021 1.018
Im1 A2−c 0.968 2.100 2.522 2.230
TS A2−c 1.042 2.200 2.402 1.597
Im2 A2−c 2.507 2.491 2.038 1.020
Im1 A2−d 0.964 2.072 2.392 2.524
TS A2−d 1.058 2.212 2.315 1.576
Im2 A2−d 2.637 2.439 2.041 1.021