Table 1.

Oxidative dissociation method reproducibility was performed with experimental replicates (n = 3) of whole butternut squash sample. For relative abundances greater than 1%, standard deviations were calculated to be less than 3%, signifying the method reproducibility for polysaccharide dissociation.

RT (min)	monosaccharide composition	relative abundance (%)	polysaccharide of origin
10.92	Hex4	17 ± 2	amylose
12.88	Hex5	14 ± 1	amylose
13.87	Hex6	9 ± 0	amylose
14.50	Hex7	7 ± 3	amylose
3.70	Hex3	5 ± 1	amylose
10.92	Hex3Pnt	4 ± 1	*
12.88	Hex4Pnt	4 ± 0	*
15.16	Hex8	4 ± 1	amylose
13.87	Hex5Pnt	3 ± 0	*
3.70	Hex2Pnt	2 ± 0	*
25.50	Hex5	2 ± 3	cellulose
19.74	Hex4	2 ± 3	cellulose
14.50	Hex6Pnt	2 ± 1	*
15.16	Hex7Pnt	2 ± 2	*
20.05	Hex13	1 ± 1	amylose
18.41	Hex11	1 ± 0	amylose
11.93	Hex3 #	1 ± 1	*
16.16	Hex9	1 ± 0	amylose
19.50	Hex12	1 ± 0	amylose
20.55	Hex14	1 ± 1	amylose
21.64	Hex16	1 ± 1	amylose

^*Not present in the oligosaccharide fingerprinting library

^#Non-reducing oligosaccharide