Table 3.

¹H and ¹³C NMR (800/201 MHz, CDCl₃) chemical shifts of triol 9.

	Aa	Ba	Ca	Da	Ea	Fa
H-1	4.80	5.08	4.71	4.76	5.58	4.78
H-2	3.28	3.62	3.38	3.45	3.56	3.39
H-3	4.22	4.26	4.01	4.12	4.11	4.03
H-4	3.35	3.82	3.76	3.74	3.88	3.63
H-5	3.86	3.88	3.97b	4.15b	3.97	3.97b
H-6a	3.70	4.06	3.94c	3.73	4.12c	3.88c
H-6b	3.63	3.72	3.82c	3.73	3.71c	3.77c
OH	2.80 (bs, 1H)	–	–	2.98 (bs, 1H)	–	–
Bn	5.51 (d, J = 10.8 Hz, 1H), 5.28 (d, J = 10.6 Hz, 1H), 5.17 (d, J = 10.5 Hz, 1H), 5.13 (d, J = 11.2 Hz, 1H), 4.96 (d, J = 11.0 Hz, 1H), 4.90 (2d, 2H), 4.84 (d, J = 11.5 Hz, 1H), 4.82–4.68 (m, 4H), 4.62–4.38 (m, 18H)
Ar	7.42 (m,2H), 7.35 (m, 4H), 7.32–7.08 (m, 61H)
C-1	100.4	100.8	99.6	98.0	98.7	98.4
C-2	77.5	78.2	78.7	80.0	77.6	79.6
C-3	73.5	81.2	80.8	80.6d	81.5d	80.6
C-4	82.1	82.4	76.5e	81.5e	80.9	82.7
C-5	71.8	72.2	71.8f	71.5	71.8f	72.4f
C-6	62.3	70.2	71.1g	62.5	70.0g	71.2g
Bn	76.62, 76.47, 76.03, 76.01, 74.52, 74.31, 73.48, 73.01, 72.96, 72.78, 72.62, 71.99, 69.96, 69.88, 69.82
Ar	139.7–137.6 (Ph ipso), 134.5–133.3 (Ar ipso), 129.9–126.6 (Ph & Ar CH)

^aThe letters A to F refers to each of the monosaccharides using normal cyclodextrin nomenclature as of Figure 1. ^bShifts may be interchanged. ^cShifts may be interchanged. ^dShifts may be interchanged. ^eShifts may be interchanged. ^fShifts may be interchanged. ^gShifts may be interchanged.