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. 2022 Sep 21;24(45):8261–8264. doi: 10.1021/acs.orglett.2c02627

Table 2. Oxidative Halogenation of Natural Productsa.

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a

All reactions were carried out using 0.5 mmol of natural product, 0.6 mmol of Selectfluor, and 1.2 mmol of TBAX (Cl, Br) in 2 mL of CH3CN. For chlorination: 100 °C, 2 h. For bromination: rt, 5 min. Conversions were calculated by 1H NMR with 1,3-dinitrobenzene as internal standard.