Table 1. Volumetric and Linear Coefficients of Unit Cell Thermal Expansion. Errors Are Given as the Average Standard Deviation, Reported to 5 sf.
| volumetric | linear |
||||
|---|---|---|---|---|---|
| sample | temperature range (°C) | ανa (10–6 K–1) | αaa (10–6 K–1) | αba (10–6 K–1) | αca (10–6 K–1) |
| MIL-118B | 110–230 | 35.572(5) | 51.795(6) | –3.1281(2) | –12.982(1) |
| 230–290 | –1.6609(3) | –8.8327(8) | –3.8524(2) | 10.795(1) | |
| (MIL-118)0.5(agZIF-62)0.5 | 110–250 | –4.9963(15) | –2.9865(7) | –4.0969(7) | 2.0710(2) |
| 250–310 | 36.628(10) | 30.507(6) | 4.8333(7) | 1.1480(1) | |
| UL-MOF-1 | 30–310 | 117.84(5) | 0.84381(20) | 18.300(5) | 90.226(22) |
| (UL-MOF-1)0.5(agZIF-62)0.5 | 30–310 | 103.22(7) | –3.3784(19) | 16.398(3) | 80.862(24) |
| MIL-53-lp | 70–310 | 2.2259(23) | 1.9377(6) | –6.3306(54) | 6.6444(34) |
| (MIL-53)0.25(agZIF-62)0.75 | 70–310 | 5.3364(123) | –4.1684(26) | 6.9688(133) | 2.5676(29) |
a
Single value using the lowest temperature of the specified temperature range.