Table 3.
Experimental Data of Trial Factors and UMN Recovery
| sonication |
[UMN]0 |
[UMN]max |
[UMN]recovery |
|||
|---|---|---|---|---|---|---|
| trial | pH | (min) | V R | mg mL−1 | mg mL−1 | mg mL−1 |
| 1322–1 | 5.0 | 30 | 1 | 3.1 | 0.8 | 0.6 |
| 1322–2 | 5.0 | 30 | 1 | 3.1 | 0.8 | 0.7 |
| 1322–3 | 5.0 | 30 | 1 | 3.1 | 0.8 | 0.6 |
| 1123–1 | 5.2 | 10 | 1 | 4.0 | 0.9 | 0.7 |
| 1123–2 | 5.2 | 10 | 1 | 3.8 | 0.8 | 0.5 |
| 1123–3 | 5.2 | 10 | 1 | 4.1 | 0.9 | 0.6 |
| 1112–1 | 5.2 | 10 | 0.8 | 2.9 | 0.9 | 0.6 |
| 1112–2 | 5.2 | 10 | 0.8 | 3.0 | 0.9 | 0.4 |
| 1112–3 | 5.2 | 10 | 0.8 | 3.0 | 0.9 | 0.5 |
| 1111–1 | 4.8 | 10 | 0.8 | 1.0 | 1.0 | 1.5b |
| 1111–2 | 4.8 | 10 | 0.8 | 1.0 | 1.0 | 1.5b |
| 1111–3 | 4.8 | 10 | 0.8 | 1.0 | 1.0 | 1.3b |
a
Experimental trials with replicates (i.e., 1, 2, 3 after the hyphen in each trial name). Numbers are experimental values based on optimization design. The [UMN] recovery is the mass concentration of UMNs recovered after extraction of PERFUMNs. Trials are ordered from best to worst performance in both yield and efficiency; 1322 was the best performance, 1123 is the first trial above the average, 1112 was the first trial below average, 1111 had the worst performance.
b
indicates values that are above the expected maximum concentration.