Fig. 10. 1 : 2 reduction of [(TMS)₂N]₂TiCl(THF) using KC₈ in the presence of N₂ generates 8·THF and a 1 : 1 reduction in pentane generates 10 (top). Crystal structures of 8·THF and 10 (bottom) with displacement ellipsoids at the 50% probability level. Hydrogen atoms and disorder were removed for clarity.