Fig. 2. Top: synthesis of 6-K by KC8 reduction of TiIII[N(TMS)2]3 in toluene. Bottom: crystal structure of 6-K with displacement ellipsoids drawn at the 50% probability level, including zoom-in of the bridging toluene showing the dihedral angle across the C5–C6–C1–C2 and C2–C3–C4–C5 planes. Hydrogen atoms and a disordered TMS group were omitted for clarity. Selected bond distance ranges (Å) and angles (°) are shown in Table S15.†.
